140414
3,5-Di-tert-butyl-2-hydroxybenzaldehyde
99%
Synonym(s):
3,5-Di-tert-butylsalicylaldehyde
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About This Item
Linear Formula:
HOC6H2[C(CH3)3]2CHO
CAS Number:
Molecular Weight:
234.33
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
99%
Form:
powder or crystals
InChI
1S/C15H22O2/c1-14(2,3)11-7-10(9-16)13(17)12(8-11)15(4,5)6/h7-9,17H,1-6H3
SMILES string
CC(C)(C)c1cc(C=O)c(O)c(c1)C(C)(C)C
InChI key
RRIQVLZDOZPJTH-UHFFFAOYSA-N
assay
99%
form
powder or crystals
mp
59-61 °C (lit.)
functional group
aldehyde
Quality Level
Related Categories
General description
3,5-Di-tert-butyl-2-hydroxybenzaldehyde undergoes condensation reaction with
- methyl-2-{N-(2′-aminoethane)}-amino-1-cyclopentenedithiocarboxylate to yield Schiff base ligand
- N,N-diethyl-2-methyl-1,4-phenylenediamine during the synthesis of copper(II) and cobalt(II) complexes of salicylaldimine
Application
3,5-Di-tert-butyl-2-hydroxybenzaldehyde was used in the synthesis of
- Mn(III)-salen complex and its diamino precursor 5,6-diamino-5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-β-L-idofuranose
- chiral Schiff base ligand for an enantioselective copper-catalyzed addition of phenylacetylene to imines
- chiral oxazolidine ligand for the enantioselective addition of diethylzinc to aldehydes
- tin Schiff base complexes with histidine analogues
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Tetrahedron Asymmetry, 18, 1124-1124 (2007)
Mild and efficient synthesis of 5, 6-diamino-5, 6-dideoxy-1, 2-O-isopropylidene-3- O -methyl-?-l-idofuranose: precursor of the first carbohydrate-derived chiral Mn (III)-salen complex.
Yan S and Klemm D.
Tetrahedron, 58(50), 10065-10071 (2002)
Tetrahedron Asymmetry, 18, 377-377 (2007)
Chunshuang Liang et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 183, 267-274 (2017-04-30)
A Schiff-base, (2,4-di-tert-butyl-6-((2-hydroxyphenyl-imino)-methyl)phenol) (L), has been improved to function as a simultaneous multi-ion probe in different optical channel. The probe changes from colorless to orangish upon being deprotonated by F
Saeid Menati et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 1033-1040 (2012-08-29)
A novel Schiff base (H(2)cddi(t)butsalen) ligand was prepared via condensation of Methyl-2-{N-(2'-aminoethane)}-amino-1-cyclopentenedithiocarboxylate(Hcden) and 3,5-di-tert-butyl-2-hydroxybenzaldehyde. The ligand and Ni(II) and Cu(II) complexes were characterized based on elemental analysis, IR, (1)H NMR, (13)C NMR, UV-Vis spectrometry and cyclic voltammetry. The structure of
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