142166
Triphenylantimony(V) diacetate
97%
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About This Item
Linear Formula:
(CH3CO2)2Sb(C6H5)3
CAS Number:
Molecular Weight:
471.16
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
Assay
97%
reaction suitability
core: antimony
reagent type: catalyst
mp
217-221 °C (lit.)
SMILES string
CC(=O)O[Sb](OC(C)=O)(c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/3C6H5.2C2H4O2.Sb/c3*1-2-4-6-5-3-1;2*1-2(3)4;/h3*1-5H;2*1H3,(H,3,4);/q;;;;;+2/p-2
InChI key
MPOFCRCFZPKTCF-UHFFFAOYSA-L
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Mio Matsumura et al.
Chemical & pharmaceutical bulletin, 63(2), 130-133 (2015-03-10)
The reaction of triarylantimony diacetates [Ar3Sb(OAc)2] with dialkyl H-phosphites [H-PO(OR)2] in the presence of a Pd(PPh3)4 (5 mol%) catalyst led to the formation of arylphosphonates in moderate to excellent yield under base-free conditions. This reaction is the first example of
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