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Merck
CN

142719

Phenyl benzoate

99%

Synonym(s):

Benzoic acid phenyl ester

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About This Item

Linear Formula:
C6H5CO2C6H5
CAS Number:
93-99-2
Molecular Weight:
198.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24848534
EC Number:
202-293-2
Beilstein/REAXYS Number:
1566346
MDL number:
MFCD00003072

Key Documents

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Product Name

Phenyl benzoate, 99%

InChI key

FCJSHPDYVMKCHI-UHFFFAOYSA-N

InChI

1S/C13H10O2/c14-13(11-7-3-1-4-8-11)15-12-9-5-2-6-10-12/h1-10H

SMILES string

O=C(Oc1ccccc1)c2ccccc2

assay

99%

form

solid

bp

298-299 °C (lit.)

mp

68-70 °C (lit.)

solubility

alcohol: freely soluble (hot)
diethyl ether: slightly soluble
water: insoluble

functional group

ester
phenoxy
phenyl

Quality Level

100

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Application

Phenyl benzoate was used in the synthesis of soluble polyimides using dianhydride/diamine derivatives.

General description

Phenyl benzoate is a phenyl ester of benzoic acid. Crystal structure of phenyl benzoate has been determined from 844 microdensitometer-measured intensities. All bond lengths and angles were reported to be normal. Phenyl benzoate undergoes Fries rearrangement catalyzed by heteropoly acids to yield the acylated phenols and esters.

Phenyl benzoate serves as a precursor that undergoes the intramolecular biaryl coupling reaction to produce the intermediate for the synthesis of (−)-steganone.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302,H315

Hazard Classifications

Acute Tox. 4 Oral - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBF6278V
S78617V
S78617
MKAA1921
09157

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Intramolecular biaryl coupling reaction of benzyl benzoate and phenyl benzoate derivatives, and its application to the formal synthesis of (-)-steganon
Takeda S, et al.
Tetrahedron, 63, 396-408 (2007)
Daun Jung et al.
Journal of applied toxicology : JAT, 36(9), 1129-1136 (2015-12-23)
In vitro testing methods for classifying sensitizers could be valuable alternatives to in vivo sensitization testing using animal models, such as the murine local lymph node assay (LLNA) and the guinea pig maximization test (GMT), but there remains a need
SYNTHESIS OF SOLUBLE HIGH Tg POLYIMIDES UTILIZING ESTER-ACID DIANHYDRIDE DERIVATIVES.
Moy TM, et al.
Advances in Polyimide Science and Technology: Proceedings of the Fourth International Conference on Polyimides (1993)
Fries rearrangement of aryl esters catalysed by heteropoly acid.
Kozhevnikova EF, et al.
Applied Catalysis A: General, 245(1), 69-78 (2003)
The crystal structure of phenyl benzoate.
Adams JM and Morsi SE.
Acta Crystallographica Section B, Structural Crystallography and Crystal Chemistry, 32(5), 1345-1347 (1976)
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Fries重排

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