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Merck
CN

143677

2-(Bromomethyl)naphthalene

96%

Synonym(s):

β-(Bromomethyl)naphthalene, β-Naphthylmethyl bromide, (Naphthalen-2-yl)methyl bromide, 2-(Bromomethyl)naphthalene, 2-Menaphthyl bromide, 2-Naphthylmethyl bromide

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About This Item

Linear Formula:
C10H7CH2Br
CAS Number:
939-26-4
Molecular Weight:
221.09
Beilstein:
636546
EC Number:
213-359-5
MDL number:
MFCD00004123
UNSPSC Code:
12352100
PubChem Substance ID:
24848601
NACRES:
NA.22

Key Documents

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Quality Level

100

Assay

96%

bp

213 °C/100 mmHg (lit.)

mp

51-54 °C (lit.)

functional group

bromo

storage temp.

2-8°C

SMILES string

BrCc1ccc2ccccc2c1

InChI

1S/C11H9Br/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-7H,8H2

InChI key

RUHJZSZTSCSTCC-UHFFFAOYSA-N

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Application

2-(Bromomethyl)naphthalene (2-BMN) can be employed as a starting material in the synthesis of 2-(fluoromethyl)naphthalene , 2-naphthylmethyl azide , 2-naphthalenecarboxaldehyde , diselenide, bis(2-naphthalenylmethyl) , 1H-1,2,3-triazole, 4,4′-(1,4-phenylene)bis[1-(2-naphthalenylmethyl).

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H314,H317

Hazard Classifications

Skin Corr. 1B - Skin Sens. 1

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBJ7258
STBJ6043
STBH2765
STBG0636V
STBC9168V

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Probing the reactivity of o-phthalaldehydic acid/methyl ester: synthesis of N-isoindolinones and 3-arylaminophthalides
Mamidyala SK and Cooper MA
Chemical Communications (Cambridge, England), 49(75), 8407-8409 (2013)
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Dimeric and trimeric triazole based molecules as a new class of Hsp90 molecular chaperone inhibitors
Terracciano S, et al.
European Journal of Medicinal Chemistry, 65(9), 464-476 (2013)
Task-specific hexaethylene glycol bridged di-cationic ionic liquids as catalysts for nucleophilic fluorination using potassium fluoride
Jadhav VH, et al.
Chemical Engineering Journal, 308, 664-668 (2017)
A novel and efficient method for the synthesis of dibenzyl diselenides
Tian F and Lu S
J. Chem. Res. (M), 2004(9), 632-633 (2004)
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