144819
1-(Trimethylsiloxy)cyclohexene
99%
Synonym(s):
1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether
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About This Item
Linear Formula:
C6H9OSi(CH3)3
CAS Number:
Molecular Weight:
170.32
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
229-675-1
Beilstein/REAXYS Number:
1859394
MDL number:
Product Name
1-(Trimethylsiloxy)cyclohexene, 99%
InChI key
SBEMOANGDSSPJY-UHFFFAOYSA-N
InChI
1S/C9H18OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h7H,4-6,8H2,1-3H3
SMILES string
C[Si](C)(C)OC1=CCCCC1
assay
99%
form
liquid
refractive index
n20/D 1.447 (lit.)
bp
64-65 °C/15 mmHg (lit.)
density
0.875 g/mL at 25 °C (lit.)
Quality Level
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Application
1-(Trimethylsiloxy)cyclohexene was used in one-pot synthesis of Δ1,9- octalone. It is intermediate to many complex compounds including natural products.
General description
1-(Trimethylsiloxy)cyclohexene undergoes Michael addition reaction with methyl vinyl ketone in the presence of dibutyltin bis(triflate).
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Find documentation for the products that you have recently purchased in the Document Library.
Organotin triflate as practical catalyst for Michael addition of enol silyl ethers.
Sato T, et al.
Tetrahedron, 47(47), 9773-9782 (1991)
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