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Merck
CN

145831

Allylamine

98%

Synonym(s):

2-Propen-1-ylamine, 3-Amino-1-propene

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About This Item

Linear Formula:
CH2=CHCH2NH2
CAS Number:
Molecular Weight:
57.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-463-9
Beilstein/REAXYS Number:
635703
MDL number:
Assay:
98%
Form:
liquid
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InChI key

VVJKKWFAADXIJK-UHFFFAOYSA-N

InChI

1S/C3H7N/c1-2-3-4/h2H,1,3-4H2

SMILES string

NCC=C

vapor density

2 (vs air)

vapor pressure

4.09 psi ( 20 °C)

assay

98%

form

liquid

expl. lim.

22 %

bp

53 °C (lit.)

mp

−88 °C (lit.)

solubility

alcohol: miscible, chloroform: miscible, diethyl ether: miscible, water: miscible

density

0.761 g/mL at 25 °C (lit.)

functional group

amine

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Application

Allylamine can be used:
  • To prepare a chemical gradient through plasma co-polymerization of octadiene and allylamine polymer on nanoporous alumina.
  • As a monomer to prepare plasma polymerized allylamine films in the study of their reactivity on Au and Si.
  • In a direct monocarboxymethylation reaction to yield N-formyl glycine derivatives.

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

Storage Class

3 - Flammable liquids

flash_point_f

-4.0 °F - closed cup

flash_point_c

-20 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

Regulatory Information

监管及禁止进口产品
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Chemical reactivity of plasma polymerized allylamine (PPAA) thin films on Au and Si: Study of the thickness influence and aging of the films.
Moreau N, et al.
Surface and Coatings Technology, 205, S462-S465 (2011)
A mild and efficient method for the one-pot monocarboxymethylation of primary amines
Gibbs Timothy JK, et al.
Synlett, 2007(10), 1573-1576 (2007)
Chemical reactivity of plasma polymerized allylamine (PPAA) thin films on Au and Si: Study of the thickness influence and aging of the films
Moreau N, et al.
Surface and Coatings Technology, 205(41), S462-S465 (2011)
Synlett, 1573-1573 (2007)
Versatile gradients of chemistry, bound ligands and nanoparticles on alumina nanopore arrays
Michelmore A, et al.
Nanotechnology, 22(41), 415601-415601 (2011)

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