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Merck
CN

147532

1,3,5-Benzenetricarbonyl trichloride

98%

Synonym(s):

Benzene-1,3,5-tricarbonyl chloride, Trimesic acid trichloride, Trimesoyl chloride

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About This Item

Linear Formula:
C6H3(COCl)3
CAS Number:
Molecular Weight:
265.48
UNSPSC Code:
12352100
NACRES:
NA.23
PubChem Substance ID:
EC Number:
224-594-8
Beilstein/REAXYS Number:
2940936
MDL number:
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Quality Level

assay

98%

form

solid

bp

180 °C/16 mmHg (lit.)

mp

32-38 °C (lit.)

solubility

chloroform: soluble 10%, clear to very slightly hazy, colorless to faintly yellow

density

1.487 g/mL at 25 °C (lit.)

SMILES string

ClC(=O)c1cc(cc(c1)C(Cl)=O)C(Cl)=O

InChI

1S/C9H3Cl3O3/c10-7(13)4-1-5(8(11)14)3-6(2-4)9(12)15/h1-3H

InChI key

UWCPYKQBIPYOLX-UHFFFAOYSA-N

General description

1,3,5-Benzenetricarbonyl trichloride reacts with propargyl alcohol to yield triprop-2-ynyl benzene-1,3,5-tricarboxylate.

Application

1,3,5-Benzenetricarbonyl trichloride was used in the synthesis of chiral azoaromatic dendrimeric systems. It was used to study the structure of activated composite membranes containing organophosphorus extractants as carriers. It was the starting material for two tritopic amides derived from 3- and 4-methylaminopyridine which self-assembled into nanoballs on treatment with palladium(II) nitrate in DMSO.


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pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Machodi Mathaba et al.
Membranes, 10(3) (2020-03-28)
Acid mine drainage is an environmental problem associated with mining operations and activities. Its treatment is essential to achieving environmental sustainability. In this study, a polyethersulphone (PES) membrane infused with chitosan is proposed as a point-of-use material for treating acid
Evaluation of structural properties of novel activated composite membranes containing organophosphorus extractants as carriers.
Oleinikova M, et al.
Langmuir, 16(2), 716-721 (2000)
Kranthikumar Tungala et al.
Carbohydrate polymers, 95(1), 295-298 (2013-04-27)
Triprop-2-ynyl benzene-1,3,5-tricarboxylate (A) is synthesized by the reaction of 1,3,5-benzenetricarbonyl trichloride with propargyl alcohol and (A) is clicked with mono-6-deoxy-6-azido-β-cyclodextrin (N3-β-CD) in the presence of copper(I) bromide catalyst. N3-β-CD has been prepared from β-cyclodextrin (β-CD) on treatment with toluenesulfonyl chloride



Global Trade Item Number

SKUGTIN
147532-2.5KG04061838737441
147532-25G04061838737458
147532-12X500G-GL04061835533114
147532-500G04061838737465
147532-10G04061838737427
147532-6X500G04061833684801
147532-100G04061838737410