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Sigma-Aldrich

Diphenylsilane

97%

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Synonym(s):
Diphenyl silane, Diphenylsilicon
Linear Formula:
(C6H5)2SiH2
CAS Number:
775-12-2
Molecular Weight:
184.31
Beilstein:
2935887
EC Number:
212-271-4
MDL number:
MFCD00003002
PubChem Substance ID:
24848906

Quality Level

100

Assay

97%

form

liquid

refractive index

n20/D 1.579 (lit.)

bp

95-97 °C/13 mmHg (lit.)

density

0.993 g/mL at 25 °C (lit.)

SMILES string

[SiH2](c1ccccc1)c2ccccc2

InChI

1S/C12H12Si/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H,13H2

InChI key

VDCSGNNYCFPWFK-UHFFFAOYSA-N

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General description

Diphenylsilane is an organosilicon compound used as an amide bond coupling reagent & alkene hydrosilylation precursor.

accessory

Product No.
Description
Pricing

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

208.4 °F - closed cup

Flash Point(C)

98 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Diphenylsilane as a coupling reagent for amide bond formation
Sayes, Morgane, et al.
Green Chemistry, 19, 5060-5064 (2017)
Saravanan Karuppiah et al.
ACS nano, 14(9), 12006-12015 (2020-09-10)
Silicon (Si) is the most promising anode candidate for the next generation of lithium-ion batteries but difficult to cycle due to its poor electronic conductivity and large volume change during cycling. Nanostructured Si-based materials allow high loading and cycling stability
Ahmad Arar et al.
Molecules (Basel, Switzerland), 25(7) (2020-04-05)
Currently, Redox Initiating Systems (RISs) of Free Radical Polymerization (FRP) are mainly based on the interaction of aromatic amines with peroxides (e.g., dibenzoyl peroxide (BPO)) that can be both toxic and unstable. In the present work, we aim to replace
Slawomir Rubinsztajn et al.
Macromolecular rapid communications, 42(5), e2000601-e2000601 (2020-12-04)
The reaction of poly(hydromethylsiloxane-co-methylphenylsiloxane) with zirconium (IV) n-propoxide in dry toluene leads to extensive scission of the siloxane chain and conversion of Si-H groups. These processes produce oligomeric siloxanes and organosilanes containing moisture sensitive propoxy and siloxy-zirconate groups. The obtained
Christopher L Rock et al.
Dalton transactions (Cambridge, England : 2003), 48(2), 461-467 (2018-11-30)
The phosphine-substituted α-diimine Ni precursor, (Ph2PPrDI)Ni, has been found to catalyze alkene hydrosilylation in the presence of Ph2SiH2 with turnover frequencies of up to 124 h-1 at 25 °C (990 h-1 at 60 °C). Moreover, the selective hydrosilylation of allylic

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