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Merck
CN

148903

Sigma-Aldrich

Diphenic anhydride

98%

Synonym(s):

2,2′-Biphenyldicarboxylic acid anhydride, Diphenic acid anhydride

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About This Item

Empirical Formula (Hill Notation):
C14H8O3
CAS Number:
Molecular Weight:
224.21
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
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Quality Level

Assay

98%

mp

225-227 °C (lit.)

SMILES string

O=C1OC(=O)c2ccccc2-c3ccccc13

InChI

1S/C14H8O3/c15-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14(16)17-13/h1-8H

InChI key

RTSGJTANVBJFFJ-UHFFFAOYSA-N

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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A Micó-Tormos et al.
Journal of chromatography. A, 1216(15), 3023-3030 (2009-02-24)
A method for the determination of fatty alcohol ethoxylates (FAEs) using diphenic anhydride as derivatization reagent and RP-HPLC separation with UV-vis detection is presented and compared to derivatization with maleic, phthalic, and other cyclic anhydrides. With these anhydrides, the reaction
M Beneito-Cambra et al.
Journal of chromatography. A, 1218(47), 8511-8518 (2011-10-14)
A method for the separation, characterization and determination of fatty alcohol ethoxylates (FAE) and alkylether sulfates (AES) in industrial and environmental samples is described. Separation of the two surfactant classes was achieved in a 50:50 methanol-water medium by retaining AES
Isabella L Karle et al.
Biopolymers, 84(5), 502-507 (2006-05-09)
In the course of our work relating to the design of a bihelical structure (I) from diphenic anhydride by tethering with cystine di-OMe, stable, hard, and rigid crystals, mp 215-218 degrees C were isolated in low yields ( approximately 2%).
M J Lerma-García et al.
Journal of chromatography. A, 1216(2), 230-236 (2008-12-17)
Aliphatic and triterpene alcohols present in vegetable oils have been identified and determined by HPLC using UV-vis and MS detection after previous derivatization with diphenic anhydride. The alcoholic fraction was obtained by saponification, extraction and TLC (according to the European
M Pawlowska et al.
Journal of chromatography. A, 666(1-2), 485-491 (1994-04-22)
New pre-column derivatizing reagents: phthalic anhydride, 3-nitrophthalic anhydride, diphenic anhydride, 1,8-naphthalic anhydride and diphenylmaleic anhydride have been developed for resolving chiral compounds having amine groups. Although all of these agents produce derivatives with high molar absorptivities, the later two also

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