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Merck
CN

149845

Thallium(I) ethoxide

Synonym(s):

Ethanol thallium salt, Ethyl alcohol thallium(I) salt, Thallium monoethoxide, Thallous ethoxide

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About This Item

Linear Formula:
TlOC2H5
CAS Number:
Molecular Weight:
249.44
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
243-786-2
MDL number:
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form

liquid

Quality Segment

reaction suitability

core: thallium, reagent type: catalyst

refractive index

n20/D 1.676 (lit.)

density

3.522 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CCO[Tl]

InChI

1S/C2H5O.Tl/c1-2-3;/h2H2,1H3;/q-1;+1

InChI key

DZFYOYRNBGNPJW-UHFFFAOYSA-N

Application

With HCl, reduces a variety of functional groups; stereoselective allylation of carbonyl compounds; in situ generation of tin enolates for directed aldol reactions.


signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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