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Merck
CN

151386

Fumaryl chloride

95%

Synonym(s):

(2E)-2-Butenedioyl dichloride, Fumaric acid chloride, Fumaric acid dichloride, Fumaric dichloride, Fumaroyl dichloride, Fumaryl dichloride

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About This Item

Linear Formula:
ClCOCH=CHCOCl
CAS Number:
627-63-4
Molecular Weight:
152.96
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24849125
EC Number:
211-005-4
Beilstein/REAXYS Number:
1721342
MDL number:
MFCD00000733
Assay:
95%
Form:
liquid

Key Documents

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Product Name

Fumaryl chloride, 95%

form

liquid

InChI key

ZLYYJUJDFKGVKB-OWOJBTEDSA-N

InChI

1S/C4H2Cl2O2/c5-3(7)1-2-4(6)8/h1-2H/b2-1+

SMILES string

ClC(=O)\C=C\C(Cl)=O

assay

95%

refractive index

n20/D 1.499 (lit.)

bp

161-164 °C (lit.)

density

1.415 g/mL at 25 °C (lit.)

functional group

acyl chloride

storage temp.

2-8°C

Quality Level

200

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Application

Fumaryl chloride was used in the preparation of high molecular weight poly(propylene fumarate).

General description

The photodissociation dynamics of fumaryl chloride was studied.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

170.6 °F - closed cup

flash_point_c

77 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
SDBB6963
SDBB6464
STBL3164
STBK9964
BCCJ2936

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Monali Kawade et al.
The journal of physical chemistry. A, 115(9), 1538-1546 (2011-02-17)
The photodissociation dynamics of fumaryl chloride (ClCO-CH═CH-COCl) has been studied in a supersonic molecular beam around 235 nm using resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) technique by detecting the nascent state of the primary chlorine atom. A single laser
Seyed Amin Mirmohammadi et al.
Materials science & engineering. C, Materials for biological applications, 68, 530-539 (2016-08-16)
Hydroxyl functionalized nano-sized POSS or ethyleneglycol as diol monomers was incorporated to hydroxyl-terminated polybutadiene (HTPBD) chain in the presence of fumaryl chloride as extender. Blue light photocrosslinking system based on camphorquinone (photoinitiator) and dimethylaminoethyl methacrylate (accelerator) was applied to cure
Sepideh Koosehgol et al.
Materials science & engineering. C, Materials for biological applications, 79, 66-75 (2017-06-21)
In the present study, polyethylene glycol fumarate (PEGF) was synthesized as a component of blend solutions via polycondensation polymerization and characterized by different tests in order to determine its functional groups and its physical properties included melting and crystallization temperature
Irrum Mushtaq et al.
Materials science & engineering. C, Materials for biological applications, 108, 110456-110456 (2020-01-12)
Under different pathological conditions, high levels of reactive oxygen species (ROS) cause substantial damage to multiple organs. To counter these ROS levels in multiple organs, we have engineered highly potent novel terpolymers. We found that combination of FDA-approved polyethylene glycol
Lucas A Kinard et al.
Nature protocols, 7(6), 1219-1227 (2012-06-02)
This protocol describes the synthesis of oligo(poly(ethylene glycol) fumarate) (OPF; 1-35 kDa; a polymer useful for tissue engineering applications) by a one-pot reaction of poly(ethylene glycol) (PEG) and fumaryl chloride. The procedure involves three parts: dichloromethane and PEG are first
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