154229
4-Methoxy-1-naphthonitrile
99%
Synonym(s):
1-Cyano-4-methoxynaphthalene
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About This Item
Linear Formula:
CH3OC10H6CN
CAS Number:
Molecular Weight:
183.21
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
227-734-6
MDL number:
Assay:
99%
Form:
liquid
InChI key
FRCZUGOIGNQOID-UHFFFAOYSA-N
InChI
1S/C12H9NO/c1-14-12-7-6-9(8-13)10-4-2-3-5-11(10)12/h2-7H,1H3
SMILES string
COc1ccc(C#N)c2ccccc12
assay
99%
form
liquid
mp
100-102 °C (lit.)
Application
4-Methoxy-1-naphthonitrile was used in the preparation of 1(endo),8b-dicyano-4-methoxy-1,2,2a-trihydrocyclobuta[a]naphthalene. It was also used to synthesize substituted azocin-2(1H)-ones.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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The synthesis of azocine derivatives by the photocycloaddition of phenols to 1-naphthonitrile and 4-methoxy-1-naphthonitrile.
Al-Jalal NA.
Journal of Photochemistry and Photobiology A: Chemistry, 54(1), 99-104 (1990)
The photocycloaddition of 4-methoxy-1-naphthonitrile and 2-methoxy-1-naphthonitrile with acrylonitrile and 3, 4-dihydro-2H-pyran: Facile additions in sunlight.
Journal of Photochemistry and Photobiology A: Chemistry, 51(3), 429-436 (1990)
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