155071
Azidotrimethylsilane
95%
Synonym(s):
Trimethylsilyl azide
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About This Item
Product Name
Azidotrimethylsilane, 95%
InChI key
SEDZOYHHAIAQIW-UHFFFAOYSA-N
InChI
1S/C3H9N3Si/c1-7(2,3)6-5-4/h1-3H3
SMILES string
C[Si](C)(C)N=[N+]=[N-]
assay
95%
form
liquid
refractive index
n20/D 1.414 (lit.)
bp
52-53 °C/175 mmHg (lit.)
density
0.868 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
Application
- A nitrogen precursor to prepare GaN nanowire via metal-organic chemical vapor deposition method.
- An electrolyte additive in Li-O2 batteries. The addition of TMSN3 results in the formation of robust solid electrolyte interphase.
- An efficient reagent in the synthesis of tetrazoles, fullerenyl azide, and α-azido oximes.
- A silylating agent in the O-trimethyl silylation of alcohols and phenols.
General description
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
42.8 °F - closed cup
flash_point_c
6 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Articles
Since the preparation of the first organic azide, phenyl azide, by Peter Griess in 1864 this energy-rich and versatile class of compounds has enjoyed considerable interest.
Click chemistry, and the copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) in particular, is a powerful new synthetic tool in polymer chemistry and material science.
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