155667
2-Chlorothiophene
96%
Synonym(s):
2-Thienyl chloride
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About This Item
Empirical Formula (Hill Notation):
C4H3ClS
CAS Number:
Molecular Weight:
118.58
Beilstein:
104652
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
96%
form
liquid
refractive index
n20/D 1.547 (lit.)
bp
127-129 °C (lit.)
density
1.286 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
Clc1cccs1
InChI
1S/C4H3ClS/c5-4-2-1-3-6-4/h1-3H
InChI key
GSFNQBFZFXUTBN-UHFFFAOYSA-N
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General description
The photodissociation dynamics of 2-chlorothiophene was studied using resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) technique.
Application
2-Chlorothiophene was used in the preparation of 5-phenylthiophene derivative.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
73.4 °F - closed cup
Flash Point(C)
23 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Marc Steinmetz et al.
Chemistry, an Asian journal, 7(6), 1256-1260 (2012-02-16)
Direct C-H phenylation of 2-ethylthiophene and 2-chlorothiophene with PhPdI(bipy) complex to form either the corresponding 4-phenyl or 5-phenylthiophene derivative is studied under stoichiometric conditions using various Lewis acids as additives. It is shown that reactions occur via the corresponding cationic
Hari P Upadhyaya
Rapid communications in mass spectrometry : RCM, 33(20), 1598-1612 (2019-05-31)
Halogenated thiophenes are an important class of compounds mostly used in the synthesis of various materials, showing unusual electronic and optical properties. The Thiophene Ring Fragmentation (TRF) process is widely used in synthetic chemistry. In this study, the fragmentation pattern
Monali Kawade et al.
The journal of physical chemistry. A, 116(44), 10656-10667 (2012-10-20)
The photodissociation dynamics of halogen-substituted thiophenes, namely, 2-chlorothiophene and 2-bromo-5-chlorothiophene, has been studied in a supersonic molecular beam around 235 nm, using resonance enhanced multiphoton ionization (REMPI) time-of-flight (TOF) technique, by detecting the nascent state of the primary halogen atoms.
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