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Merck
CN

15587

Borane dimethyl sulfide complex

technical, >90% in dimethyl sulfide

Synonym(s):

BMS, Borane methyl sulfide complex, Dimethyl sulfide borane, Trihydro[thiobis[methane]]boron

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About This Item

Linear Formula:
(CH3)2S · BH3
CAS Number:
13292-87-0
Molecular Weight:
75.97
PubChem Substance ID:
24849576
UNSPSC Code:
12352000
MDL number:
MFCD00013189
Beilstein/REAXYS Number:
3663489

Key Documents

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SMILES string

B.CSC

grade

technical

reaction suitability

reagent type: reductant

concentration

>90% in dimethyl sulfide

density

0.801 g/mL at 20 °C (lit.)

storage temp.

2-8°C

Application

Reactant used as a regioselective reducing agent

Reactant involved in:
  • Hydroboration / oxidation
  • Synthesis of cage compounds

Other Notes

Convenient and stable source of borane for hydroborations, reviews ; Selective reduction of α-hydroxyesters

signalword

Danger

supp_hazards

EUH014

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

64.4 °F

flash_point_c

18 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Water-react. 1

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
STBD3011V
STBD1888V
STBC2772V
STBC5613V
STBC5612V

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H.C. Brown et al.
The Journal of Organic Chemistry, 47, 3153-3153 (1982)
S. Krishnamurthy
Tetrahedron Letters, 23, 3315-3315 (1982)
S. Saito et al.
Chemistry Letters (Jpn), 1389-1389 (1984)
R.O. Hutchins et al.
Organic preparations and procedures international, 13, 225-225 (1981)
Isidoro González-Álvaro et al.
Rheumatology (Oxford, England), 54(7), 1200-1209 (2014-12-21)
The aim of this study was to establish guidelines for the optimization of biologic therapies for health professionals involved in the management of patients with RA, AS and PsA. Recommendations were established via consensus by a panel of experts in
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