158259
O-Methyl-L-tyrosine
98%
Synonym(s):
4-Methoxy-L-phenylalanine
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About This Item
Linear Formula:
CH3OC6H4CH2CH(NH2)CO2H
CAS Number:
Molecular Weight:
195.22
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
EC Number:
228-333-9
Beilstein/REAXYS Number:
2212726
MDL number:
InChI key
GEYBMYRBIABFTA-VIFPVBQESA-N
InChI
1S/C10H13NO3/c1-14-8-4-2-7(3-5-8)6-9(11)10(12)13/h2-5,9H,6,11H2,1H3,(H,12,13)/t9-/m0/s1
SMILES string
COc1ccc(C[C@H](N)C(O)=O)cc1
assay
98%
optical activity
[α]25/D −7°, c = 0.5 in 1 M HCl
reaction suitability
reaction type: solution phase peptide synthesis
mp
259-261 °C (dec.) (lit.)
application(s)
peptide synthesis
storage temp.
2-8°C
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Debbie Dewaele et al.
Rapid communications in mass spectrometry : RCM, 30(6), 719-730 (2016-02-13)
Melphalan is a frequently used chemotherapeutical agent for the treatment of myeloma, breast cancer, ovarian cancer and sarcoma of soft tissue. A good knowledge of the reactivity of the drug toward the different amino acids, e.g. covalent adduct formation, is
Ma Diarey Tianero et al.
Nature microbiology, 4(7), 1149-1159 (2019-04-03)
Marine sponges often house small-molecule-producing symbionts extracellularly in their mesohyl, providing the host with a means of chemical defence against predation and microbial infection. Here, we report an intriguing case of chemically mediated symbiosis between the renieramycin-containing sponge Haliclona sp.
Jeffrey K Takimoto et al.
ACS chemical biology, 6(7), 733-743 (2011-05-07)
Unnatural amino acids (Uaas) can be translationally incorporated into proteins in vivo using evolved tRNA/aminoacyl-tRNA synthetase (RS) pairs, affording chemistries inaccessible when restricted to the 20 natural amino acids. To date, most evolved RSs aminoacylate Uaas chemically similar to the
Ning Wu et al.
Journal of the American Chemical Society, 126(44), 14306-14307 (2004-11-04)
We have developed a second orthogonal tRNA/synthetase pair for use in yeast based on the Escherichia coli tRNALeu/leucyl tRNA-synthetase pair. Using a novel genetic selection, we have identified a series of synthetase mutants that selectively charge the amber suppresor tRNA
S E Shoelson et al.
The Journal of biological chemistry, 264(14), 7831-7836 (1989-05-15)
The receptors for insulin and epidermal growth factor undergo tyrosine autophosphorylation in response to ligand stimulation, while pp60v-src is an unregulated tyrosine kinase. In this report we show that each of the kinases phosphorylates an exogenous peptide that corresponds to
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