160342
2-Fluoroethanol
95%
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About This Item
Linear Formula:
FCH2CH2OH
CAS Number:
Molecular Weight:
64.06
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-740-2
Beilstein/REAXYS Number:
1730857
MDL number:
Assay:
95%
Form:
liquid
InChI key
GGDYAKVUZMZKRV-UHFFFAOYSA-N
InChI
1S/C2H5FO/c3-1-2-4/h4H,1-2H2
SMILES string
OCCF
vapor pressure
16 mmHg ( 20 °C)
assay
95%
form
liquid
bp
103 °C/757 mmHg (lit.)
mp
−26.5 °C (lit.)
density
1.091 g/mL at 25 °C (lit.)
General description
The microwave spectra of two isotopic species of 2-fluoroethanol have been investigated. The Gg′ conformer of 2-fluoroethanol was isolated in low-temperature noble gas matrices. Single-photon IR photolysis of 2-fluoroethanol in solid argon has been investigated.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Oral - Flam. Liq. 3
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
93.2 °F - closed cup
flash_point_c
34 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Site-selective infrared photoisomerizations of 2-fluoroethanol in low-temperature matrices
Pourcin J, et al.
Journal of Molecular Spectroscopy, 109(1) (1985)
Infrared laser photoisomerization of 2-fluoroethanol in argon.
Hoffman III WF and Shirk JS.
Chemical Physics, 78(3), 331-338 (1983)
T J Tewson et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 21(6), 559-564 (1980-06-01)
No-carrier-added [18F] fluoroethanol has been prepared by two routes. The first involves fluoride-ion displacement on alpha-p-toluene sulfonyl ethyl glycolate followed by reduction of the alpha-fluoroethyl acetate. The second involves a ring-opening reaction on glycol sulfite to give an alpha-fluorosulfinic acid
Nicole Borho et al.
Journal of the American Chemical Society, 130(18), 5916-5921 (2008-04-12)
The conformational isomerism of the propylene oxide (PO)...2-fluoroethanol (FE) complex has been investigated using molecular beam Fourier-transform microwave spectroscopy complemented with high level ab initio calculations. Rotational transitions of three different binary conformers have been observed experimentally. On the basis
Microwave Spectrum and Intramolecular Hydrogen Bonding in 2-Fluoroethanol.
Buckton KS and Azrak RG.
J. Chem. Phys. , 52(11), 5652-5655 (1970)
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