16120
Bromoacetyl chloride
≥95% (GC)
Synonym(s):
2-Bromo-1-chloro-ethanal, 2-Bromoacetyl chloride
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About This Item
Linear Formula:
BrCH2COCl
CAS Number:
Molecular Weight:
157.39
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
244-790-7
Beilstein/REAXYS Number:
1209323
MDL number:
Assay:
≥95% (GC)
InChI key
SYZRZLUNWVNNNV-UHFFFAOYSA-N
InChI
1S/C2H2BrClO/c3-1-2(4)5/h1H2
SMILES string
ClC(=O)CBr
assay
≥95% (GC)
refractive index
n20/D 1.495
bp
127-128 °C (lit.)
density
1.89 g/mL at 20 °C
functional group
acyl chloride, bromo
storage temp.
2-8°C
Quality Level
Related Categories
General description
The competitive photodissociation of bromoacetyl chloride has been studied by ab initio methods.
Application
Bromoacetyl chloride was used in the synthesis of α,α-disubstituted thioisomünchnones. It was also used in the preparation of 1,3-dibromoacetone.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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S S Husain et al.
The Biochemical journal, 108(5), 855-859 (1968-08-01)
Papain was irreversibly inhibited by 1,3-dibromoacetone, a reagent designed to react first with the active-site cysteine residue and subsequently with a second nucleophile. The molecular weight of the inhibited enzyme was indistinguishable from that of papain itself, and no evidence
Cycloaddition chemistry of anhydro-4-hydroxy-1, 3-thiazolium hydroxides (thioisomunchnones) for the synthesis of heterocycles.
Padwa A, et al.
Synthesis, 1994(9), 993-1004 (1994)
Non-adiabatic effects in the photodissociation of bromoacetyl chloride.
Bacchus-Montabonel M-C, et al.
Chemical Physics Letters, 374(3), 307-313 (2003)
Xueqi Sun et al.
International journal of biological macromolecules, 152, 349-358 (2020-02-23)
In this study, a new class of chitosan derivatives possessing sulfonium salts was synthesized, and characterized by FT-IR, 1H NMR, 13C NMR, and elemental analyses. IR spectra, 1H NMR and 13C NMR of the structural units of these polymers validated
Azam Sargazi et al.
Colloids and surfaces. B, Biointerfaces, 171, 150-158 (2018-07-20)
Hyaluronic acid (HA) is increasingly investigated for biomedical applications such as regenerative medicine, aesthetic medicine, and drug delivery. Accordingly, conjugation of HA to PEGylated MNPs could increase the active targeting ability of nano-drug carriers toward CD44 receptors and be useful
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