16120
Bromoacetyl chloride
≥95% (GC)
Synonym(s):
2-Bromo-1-chloro-ethanal, 2-Bromoacetyl chloride
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About This Item
Linear Formula:
BrCH2COCl
CAS Number:
Molecular Weight:
157.39
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
244-790-7
Beilstein/REAXYS Number:
1209323
MDL number:
Assay:
≥95% (GC)
InChI key
SYZRZLUNWVNNNV-UHFFFAOYSA-N
InChI
1S/C2H2BrClO/c3-1-2(4)5/h1H2
SMILES string
ClC(=O)CBr
assay
≥95% (GC)
refractive index
n20/D 1.495
bp
127-128 °C (lit.)
density
1.89 g/mL at 20 °C
functional group
acyl chloride, bromo
storage temp.
2-8°C
Quality Level
Related Categories
General description
The competitive photodissociation of bromoacetyl chloride has been studied by ab initio methods.
Application
Bromoacetyl chloride was used in the synthesis of α,α-disubstituted thioisomünchnones. It was also used in the preparation of 1,3-dibromoacetone.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Cycloaddition chemistry of anhydro-4-hydroxy-1, 3-thiazolium hydroxides (thioisomunchnones) for the synthesis of heterocycles.
Padwa A, et al.
Synthesis, 1994(9), 993-1004 (1994)
Xueqi Sun et al.
International journal of biological macromolecules, 152, 349-358 (2020-02-23)
In this study, a new class of chitosan derivatives possessing sulfonium salts was synthesized, and characterized by FT-IR, 1H NMR, 13C NMR, and elemental analyses. IR spectra, 1H NMR and 13C NMR of the structural units of these polymers validated
S S Husain et al.
The Biochemical journal, 108(5), 855-859 (1968-08-01)
Papain was irreversibly inhibited by 1,3-dibromoacetone, a reagent designed to react first with the active-site cysteine residue and subsequently with a second nucleophile. The molecular weight of the inhibited enzyme was indistinguishable from that of papain itself, and no evidence
Non-adiabatic effects in the photodissociation of bromoacetyl chloride.
Bacchus-Montabonel M-C, et al.
Chemical Physics Letters, 374(3), 307-313 (2003)
Azam Sargazi et al.
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