161705
Di-2-pyridyl ketone oxime
98%
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About This Item
Empirical Formula (Hill Notation):
C11H9N3O
CAS Number:
Molecular Weight:
199.21
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
216-349-9
MDL number:
Assay:
98%
InChI key
KLOQKBNABUIDIU-UHFFFAOYSA-N
InChI
1S/C11H9N3O/c15-14-11(9-5-1-3-7-12-9)10-6-2-4-8-13-10/h1-8,15H
SMILES string
O\N=C(\c1ccccn1)c2ccccn2
assay
98%
mp
142-143 °C (lit.)
functional group
amine, oxime
storage temp.
2-8°C
General description
Di-2-pyridyl ketone oxime forms hexanuclear clusters with extremely rare manganese oxidation-state combinations. It forms neutral binuclear and cationic trinuclear, pentanuclear or hexanuclear complexes in copper chemistry.
Application
Di-2-pyridyl ketone oxime was used as a standard in the metal assay for determination of cobalt. It may be employed as metal-complexing agent.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Tereza Afrati et al.
Dalton transactions (Cambridge, England : 2003), (25)(25), 2658-2668 (2007-06-20)
The use of di-2-pyridyl ketone oxime (Hpko)/X- "blends" (X- = OH-, Cl-, ClO4-) in copper chemistry has yielded neutral binuclear and cationic trinuclear, pentanuclear or hexanuclear complexes. Various synthetic procedures have led to the synthesis of compounds [Cu5(pko)7].[ClO4]3.2CH3OH.2H2O (1), [Cu3(pko)3(OH)(Cl)]2[Ph4B]2.4DMF.2H2O
Constantinos J Milios et al.
Dalton transactions (Cambridge, England : 2003), (3)(3), 501-511 (2005-01-27)
The use of di-2-pyridyl ketone oxime, (py)2CNOH, in manganese carboxylate chemistry has been investigated. Using a variety of synthetic routes complexes [Mn(O2CPh)2{(py)2CNOH}2].0.25H2O (1.0.25H2O), Mn4(O2CPh)2{(py)2CO2}2{(py)2CNO}2Br2].MeCN (2.MeCN), [Mn4(O2CPh)2{(py)2CO2}2{(py)2CNO}2Cl(2)].2MeCN (3.2MeCN), [Mn4(O2CMe)2{(py)2CO2}2{(py)2CNO}2Br2].2MeCN (4.2MeCN), [Mn4(O2CMe)2{(py)2CO2}2{(py)2CNO}2(NO3)2].MeCN.H2O (5.MeCN.H2O) and [Mn2(O2CCF3)2(hfac)2{(py)2CNOH}2] (6) have been isolated in good yields.
M W Reeves et al.
Journal of clinical microbiology, 14(1), 48-54 (1981-07-01)
A total of 13 egg lecithins, 12 beef heart lecithins, and 15 beef heart cardiolipins were assayed for the ability to function in the Venereal Disease Research Laboratory microflocculation test, as well as for purity, fatty acid composition, free amines
Paul V Bernhardt et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 8(8), 866-880 (2003-10-18)
Di-2-pyridyl ketone isonicotinoyl hydrazone (HPKIH) and a range of its analogues comprise a series of monobasic acids that are capable of binding iron (Fe) as tridentate ( N, N, O) ligands. Recently, we have shown that these chelators are highly
Constantinos C Stoumpos et al.
Inorganic chemistry, 49(10), 4388-4390 (2010-04-16)
The use of phenyl-2-pyridyl ketone oxime and di-2-pyridyl ketone oxime in Mn chemistry has led to hexanuclear clusters with unprecedented (Mn(II)(4)Mn(III)Mn(IV)) or extremely rare (Mn(II)Mn(III)(5) and Mn(II)(3)Mn(III)(3)) metal oxidation-state combinations and uncommon structural motifs.
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