161772
β-Methoxystyrene, mixture of cis and trans
technical grade, 90%
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About This Item
Linear Formula:
C6H5CH=CHOCH3
CAS Number:
Molecular Weight:
134.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
90%
Form:
liquid
InChI
1S/C9H10O/c1-10-8-7-9-5-3-2-4-6-9/h2-8H,1H3
SMILES string
COC=Cc1ccccc1
InChI key
CTHJQRHPNQEPAB-UHFFFAOYSA-N
grade
technical grade
assay
90%
form
liquid
refractive index
n20/D 1.565 (lit.)
bp
50-56 °C/0.6 mmHg (lit.)
density
1.001 g/mL at 25 °C (lit.)
functional group
ether, phenyl
storage temp.
2-8°C
General description
β-Methoxystyrene undergoes reduction in the presence of calcium in liquid ammonia to yield methyl phenethyl ether.
Application
β-Methoxystyrene was used in the synthesis of trans, trans-1-(aminomethyl)-2-methoxy-3-phenylcyclopropane.
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Calcium metal in liquid ammonia for selective reduction of organic compounds.
Hwu JH, et al.
The Journal of Organic Chemistry, 61(4), 1493-1499 (1996)
Xingliang Lu et al.
The Journal of organic chemistry, 61(25), 8961-8966 (1996-12-13)
trans,trans-1-(Aminomethyl)-2-methoxy-3-phenylcyclopropane (3) was synthesized in three steps from (Z)-beta-methoxystyrene and ethyl diazoacetate. Compound 3 was shown to be a substrate and inactivator of mitochondrial beef liver monoamine oxidase (MAO) with a partition ratio of 1428. MAO-catalyzed oxidation of 3 produces
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