165263
Ethyl 2-ethylacetoacetate
90%
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About This Item
Linear Formula:
CH3COCH(C2H5)COOC2H5
CAS Number:
Molecular Weight:
158.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-151-6
Beilstein/REAXYS Number:
636286
MDL number:
Assay:
90%
Form:
liquid
InChI key
OKANYBNORCUPKZ-UHFFFAOYSA-N
InChI
1S/C8H14O3/c1-4-7(6(3)9)8(10)11-5-2/h7H,4-5H2,1-3H3
SMILES string
CCOC(=O)C(CC)C(C)=O
assay
90%
form
liquid
bp
87-189 °C/743 mmHg (lit.)
density
0.981 g/mL at 25 °C (lit.)
functional group
ester, ketone
Application
Ethyl 2-ethylacetoacetate was used in the synthesis of 2-alkylidenetetrahydrofurans, diphenyllead(IV) thiosemicarbazonates and pyrazolonates. It was used as starting reagent in the synthesis of 2-ethylfumaric acid.
Storage Class
10 - Combustible liquids
wgk
WGK 1
flash_point_f
156.2 °F - closed cup
flash_point_c
69 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Regulatory Information
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Diphenyllead (IV) thiosemicarbazonates and pyrazolonates: Synthesis and characterization.
Casas JS, et al.
Polyhedron, 28(5), 1029-1039 (2009)
Hans Raj et al.
Applied microbiology and biotechnology, 94(2), 385-397 (2011-10-19)
Methylaspartate ammonia lyase (MAL; EC 4.3.1.2) catalyzes the reversible addition of ammonia to mesaconate to give (2S,3S)-3-methylaspartate and (2S,3R)-3-methylaspartate as products. MAL is of considerable biocatalytic interest because of its potential use for the asymmetric synthesis of substituted aspartic acids
Efficient synthesis of functionalized furans and benzofurans based on a '[3+ 2] cyclization/oxidation'strategy.
Bellur E, et al.
Tetrahedron Letters, 46(13), 2185-2187 (2005)
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