166804
Dibenzyl azodicarboxylate
technical grade, 90%
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About This Item
Linear Formula:
C6H5CH2OCON=NCOOCH2C6H5
CAS Number:
Molecular Weight:
298.29
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-508-0
Beilstein/REAXYS Number:
2298734
MDL number:
Assay:
90%
Form:
solid
grade
technical grade
Quality Segment
assay
90%
form
solid
mp
43-47 °C (lit.)
functional group
azo, phenyl
storage temp.
2-8°C
SMILES string
O=C(OCc1ccccc1)\N=N\C(=O)OCc2ccccc2
InChI
1S/C16H14N2O4/c19-15(21-11-13-7-3-1-4-8-13)17-18-16(20)22-12-14-9-5-2-6-10-14/h1-10H,11-12H2/b18-17+
InChI key
IRJKSAIGIYODAN-ISLYRVAYSA-N
General description
Dibenzyl azodicarboxylate undergoes[4+2] cycloaddition reaction with glycal to yield 2-aminoglycosides.
Application
Dibenzyl azodicarboxylate was used as electrophilic reagent in the synthesis of C-glycosyl α-amino acids via proline-catalyzed α-amination of C-glycosylalkyl aldehydes. It was used in enantioselective synthesis of optically active pyrazolidine derivatives.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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