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167185

Methyl 2-bromopropionate

Name: Methyl 2-bromopropionate
Brand: ALDRICH

98%

Synonym(s):

(±)-2-Bromopropionic acid methyl ester, (±)-Methyl 2-bromopropionate, 2-Bromopropanoic acid methyl ester, 2-Bromopropionic acid methyl ester, Methyl (±)-α-bromopropionate

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About This Item

Linear Formula:

CH₃CHBrCO₂CH₃

CAS Number:

5445-17-0

Molecular Weight:

167.00

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24850199

EC Number:

226-642-3

Beilstein/REAXYS Number:

1720592

MDL number:

MFCD00000143

Assay:

98%

Form:

liquid

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Properties

Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.451 (lit.)

bp

51 °C/19 mmHg (lit.)

solubility

water: insoluble

density

1.497 g/mL at 25 °C (lit.)

functional group

bromo, ester

SMILES string

COC(=O)C(C)Br

InChI

1S/C4H7BrO2/c1-3(5)4(6)7-2/h3H,1-2H3

InChI key

ACEONLNNWKIPTM-UHFFFAOYSA-N

Description

Application

Methyl 2-bromopropionate was used as initiator during the synthesis of polymer brushes with single-walled carbon nanotubes as backbones. It was used as starting reagent for the synthesis of 2-¹⁸F-fluoropropionic acid, positron emission tomography imaging agent for prostate cancer.

pictograms

GHS02,GHS05,GHS07

signalword

Danger

hcodes

H226,H314,H335

pcodes

P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

125.6 °F - closed cup

flash_point_c

52 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Polymer brushes on single-walled carbon nanotubes by atom transfer radical polymerization of n-butyl methacrylate.

Shuhui Qin et al.

Journal of the American Chemical Society, 126(1), 170-176 (2004-01-08)

Polymer brushes with single-walled carbon nanotubes (SWNT) as backbones were synthesized by grafting n-butyl methacrylate (nBMA) from the ends and sidewalls of SWNT via atom transfer radical polymerization (ATRP). Carboxylic acid groups on SWNT were formed by nitric acid oxidation.

p-Substituted Tris(2-pyridylmethyl)amines as Ligands for Highly Active ATRP Catalysts: Facile Synthesis and Characterization.

Alan E Enciso et al.

Angewandte Chemie (International ed. in English) (2020-05-18)

A facile and efficient two-step synthesis of p-substituted tris(2-pyridylmethyl)amine (TPMA) ligands to form Cu complexes with the highest activity to date in atom transfer radical polymerization (ATRP) is presented. In the divergent synthesis, p-Cl substituents in tris(4-chloro-2-pyridylmethyl)amine (TPMA3Cl ) were

Single-Electron Transfer Living Radical Polymerization Platform to Practice, Develop, and Invent.

Gerard Lligadas et al.

Biomacromolecules, 18(10), 2981-3008 (2017-08-30)

The most fundamental aspects of single-electron transfer (SET) principles are presented. They are discussed according to different definitions used by expert practitioners and are applied to SET living radical polymerization (SET-LRP) according to the definition of the division of organic

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Global Trade Item Number

SKU	GTIN
167185-100G	04061838749420
167185-25G	04061838749437