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About This Item
Empirical Formula (Hill Notation):
C6H8N2O2S
CAS Number:
Molecular Weight:
172.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
389057
assay
≥97%
form
solid
SMILES string
Cc1ccc(nc1)S(N)(=O)=O
InChI
1S/C6H8N2O2S/c1-5-2-3-6(8-4-5)11(7,9)10/h2-4H,1H3,(H2,7,9,10)
InChI key
HXURYNQXMBRJLU-UHFFFAOYSA-N
Application
5-Methyl-2-pyridinesulfonamide was used to develop a copper-catalyzed aziridination protocol.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Hoon Han et al.
Organic letters, 6(22), 4109-4112 (2004-10-22)
[reaction: see text] We have developed, on the basis of a chelation-strategy, an efficient copper-catalyzed aziridination protocol with the use of 5-methyl-2-pyridinesulfonamide and PhI(OAc)(2). The reaction proceeds smoothly under mild conditions to give aziridines in moderate to good yields in
