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Merck
CN

172626

Dodecyltriphenylphosphonium bromide

98%

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About This Item

Linear Formula:
CH3(CH2)11P(C6H5)3Br
CAS Number:
Molecular Weight:
511.52
UNSPSC Code:
12352002
PubChem Substance ID:
EC Number:
239-538-8
MDL number:
Assay:
98%
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InChI key

NSIFOGPAKNSGNW-UHFFFAOYSA-M

InChI

1S/C30H40P.BrH/c1-2-3-4-5-6-7-8-9-10-20-27-31(28-21-14-11-15-22-28,29-23-16-12-17-24-29)30-25-18-13-19-26-30;/h11-19,21-26H,2-10,20,27H2,1H3;1H/q+1;/p-1

SMILES string

[Br-].CCCCCCCCCCCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

assay

98%

reaction suitability

reaction type: C-C Bond Formation

mp

85-88 °C (lit.)

Application

Involved in comparative electrochemical studies of anticorrosion efficiency of nanocomposite coatings

Intercalating agent for modifying anticorrosion, gas barrier, mechanical and thermal properties of nanocomposite coatings

Mediator for reactions of nitrophenyl acetate

Studies of:
  • Nucleophilic substitution kinetics of sulfonate ester
  • Intercalated polyester / silicate nanocomposites
  • Thermal stability of quaternary phosphonium-modified montmorillonites in silicate layered polymer nanocomposites

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Meera Shanmuganathan et al.
Analytica chimica acta, 773, 24-36 (2013-04-09)
High quality assays are needed in drug discovery to reduce the high attrition rate of lead compounds during primary screening. Capillary electrophoresis (CE) represents a versatile micro-separation technique for resolution of enzyme-catalyzed reactions, including substrate(s), product(s), cofactor(s) and their stereoisomers
Ben C Chung et al.
Science (New York, N.Y.), 341(6149), 1012-1016 (2013-08-31)
MraY (phospho-MurNAc-pentapeptide translocase) is an integral membrane enzyme that catalyzes an essential step of bacterial cell wall biosynthesis: the transfer of the peptidoglycan precursor phospho-MurNAc-pentapeptide to the lipid carrier undecaprenyl phosphate. MraY has long been considered a promising target for
Kuo-Ting Chen et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(3), 834-838 (2012-12-12)
Breaking down barriers: A rapid, inexpensive preparation of the structurally complex mycobacterial N-glycolyl Lipid I, Lipid II, and their analogues from a range of different synthetic N-glycolyl and N-glycinyl Park's nucleotides is described (see scheme). The biotransformations were catalyzed by a readily
Yajun Liu et al.
The Journal of biological chemistry, 287(53), 44406-44417 (2012-11-08)
Catechins (flavan-3-ols), the most important secondary metabolites in the tea plant, have positive effects on human health and are crucial in defense against pathogens of the tea plant. The aim of this study was to elucidate the biosynthetic pathway of
Kang Zhou et al.
Microbial cell factories, 11, 148-148 (2012-11-15)
Recombinant proteins are routinely overexpressed in metabolic engineering. It is well known that some over-expressed heterologous recombinant enzymes are insoluble with little or no enzymatic activity. This study examined the solubility of over-expressed homologous enzymes of the deoxyxylulose phosphate pathway

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