17457
Methyl α-bromoisobutyrate
≥99.0% (GC)
Synonym(s):
Methyl 2-bromo-2-methylpropionate
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About This Item
Linear Formula:
(CH3)2CBrCOOCH3
CAS Number:
Molecular Weight:
181.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
245-657-6
Beilstein/REAXYS Number:
1209484
MDL number:
Assay:
≥99.0% (GC)
Form:
liquid
Quality Level
assay
≥99.0% (GC)
form
liquid
density
1.399 g/mL at 20 °C (lit.)
functional group
bromo, ester
SMILES string
COC(=O)C(C)(C)Br
InChI
1S/C5H9BrO2/c1-5(2,6)4(7)8-3/h1-3H3
InChI key
PQUSVJVVRXWKDG-UHFFFAOYSA-N
Application
Methyl α-bromoisobutyrate was used in Reformatsky reaction to prepare 1,4-disubstituted 3,3-dimethylazetidin-2-ones.
Atom Transfer Radical Polymerization (ATRP) initiator that will generate a polymer with a methyl end group
signalword
Warning
hcodes
Hazard Classifications
Flam. Liq. 3
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
120.2 °F - closed cup
flash_point_c
49 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Protocols
Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.
Reformatsky reaction of methyl ?-bromoisobutyrate with Schiff bases derived from salicylaldehyde and 2-hydroxynaphthalene-1-carbaldehyde.
Russ. J. Org. Chem., 40(6), 834-836 (2004)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| CDS007440-5MG | 04061828988105 |
| 17457-100ML | 04061838752024 |