175064
Nitrosyl tetrafluoroborate
95%
Synonym(s):
Nitrosonium tetrafluoroborate
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About This Item
Linear Formula:
NOBF4
CAS Number:
Molecular Weight:
116.81
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
Assay
95%
reaction suitability
reagent type: oxidant
storage temp.
2-8°C
SMILES string
N#[O+].F[B-](F)(F)F
InChI
1S/BF4.NO/c2-1(3,4)5;1-2/q-1;+1
InChI key
KGCNVGDHOSFKFT-UHFFFAOYSA-N
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Application
Nitrosyl tetrafluoroborate is an efficient nitrosating and diazotizing agent. It reacts with alcohols and secondary amines to yield alkyl nitrites and nitrosamines, respectively. It reacts with primary amines to yield diazonium tetrafluoroborates. NOBF4 is also a mild oxidant and commonly used for single electron transfer oxidation.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Nitrosonium Tetrafluoroborate.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Fraser G L Parlane et al.
Nature communications, 8(1), 1761-1761 (2017-11-28)
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C Würth et al.
Nanoscale, 9(12), 4283-4294 (2017-03-16)
The rational design of brighter upconversion nanoparticles (UCNPs) requires a better understanding of the radiationless deactivation pathways in these materials. Here, we demonstrate the potential of excitation power density (P)-dependent studies of upconversion (UC) luminescence intensities, slope factors, and absolute
S Mohr et al.
FEBS letters, 348(3), 223-227 (1994-07-18)
Previous studies have suggested that glyceraldehyde-3-phosphate dehydrogenase (GAPDH) undergoes covalent modification of an active site thiol by a NO.-induced [32P]NAD(+)-dependent mechanism. However, the efficacy of GAPDH modification induced by various NO donors was found to be independent of spontaneous rates
J Li et al.
Biochemical and biophysical research communications, 240(2), 419-424 (1997-12-06)
The caspases are a family of at least 10 human cysteine proteases that participate in cytokine maturation and in apoptotic signal transduction and execution mechanisms. Peptidic inhibitors of these enzymes are capable of blocking cytokine maturation and apoptosis, demonstrating their
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