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Merck
CN

176230

Triethyloxonium tetrafluoroborate solution

1.0 M in methylene chloride

Synonym(s):

Et3OBF4, Meerwein′s reagent, Triethyloxonium fluoroborate

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About This Item

Linear Formula:
(C2H5)3O(BF4)
CAS Number:
368-39-8
Molecular Weight:
189.99
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
24850566
MDL number:
MFCD00044423
Beilstein/REAXYS Number:
3598090

Key Documents

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Product Name

Triethyloxonium tetrafluoroborate solution, 1.0 M in methylene chloride

InChI

1S/C6H15O.BF4/c1-4-7(5-2)6-3;2-1(3,4)5/h4-6H2,1-3H3;/q+1;-1

SMILES string

F[B-](F)(F)F.CC[O+](CC)CC

InChI key

IYDQMLLDOVRSJJ-UHFFFAOYSA-N

concentration

1.0 M in methylene chloride

density

1.328 g/mL at 25 °C

functional group

ether

storage temp.

2-8°C

Quality Level

100

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Application

Used in the preparation of ω-aminoesters from lactams.

signalword

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system

supp_hazards

EUH014

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBS7756
SHBS2484
SHBR9534
SHBR3183
SHBQ3641

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Synthetic Communications, 18, 1625-1625 (1988)
J Aguado et al.
Biotechnology and applied biochemistry, 17 ( Pt 1), 49-55 (1993-02-01)
beta-Glucosidase from Penicillium funiculosum was immobilized on nylon powder previously activated with triethyloxonium tetrafluoroborate, 1,2-diaminoethane and glutaraldehyde. The activation of the nylon powder and the immobilization processes were studied and optimized for the enzyme and the matrix. A high activity
Some detoxification methods for N-nitrosamine-contaminated wastes.
M Castegnaro et al.
IARC scientific publications, (41)(41), 151-157 (1982-01-01)
R Ben Avraham et al.
FEBS letters, 180(2), 239-242 (1985-01-28)
Treatment of trypsin with triethyloxonium tetrafluoroborate at pH 8, 25 degrees C, results in abolition of binding to the enzyme of specific cationic substrates and inhibitors. The binding constant of soybean trypsin inhibitor to ethylated trypsin is 10000-fold smaller than
Itedale Namro Redwan et al.
The Journal of organic chemistry, 77(16), 7071-7075 (2012-07-20)
This note describes a rapid and mild strategy for the loading of alcohols and anilines onto a polystyrene triphenylmethyl (trityl) resin. High loadings were obtained in a matter of minutes by treating resin-bound trityl chloride with triethyloxonium tetrafluoroborate followed by
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