177180
Methoxyacetone
95%
Synonym(s):
Methoxy-2-propanone
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About This Item
Linear Formula:
CH3COCH2OCH3
CAS Number:
Molecular Weight:
88.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
227-549-0
Beilstein/REAXYS Number:
1560175
MDL number:
Assay:
95%
Form:
liquid
Product Name
Methoxyacetone, 95%
InChI key
CUZLJOLBIRPEFB-UHFFFAOYSA-N
InChI
1S/C4H8O2/c1-4(5)3-6-2/h3H2,1-2H3
SMILES string
COCC(C)=O
assay
95%
form
liquid
refractive index
n20/D 1.397 (lit.)
bp
118 °C (lit.)
density
0.957 g/mL at 25 °C (lit.)
functional group
ether
ketone
Quality Level
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Application
Methoxyacetone was used in the synthesis of doubly borylated enolates.
General description
The gas-phase basicity of methoxyacetone was studied.
signalword
Warning
hcodes
Hazard Classifications
Flam. Liq. 3
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
77.0 °F - closed cup
flash_point_c
25 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Atsushi Abiko et al.
Journal of the American Chemical Society, 124(36), 10759-10764 (2002-09-05)
The novel doubly borylated enolate is identified as an intermediate of the double aldol reaction of acetate esters. As a precursor to the formation of the doubly borylated enolate, carbon-bound boron enolates of carboxylic esters are spectroscopically characterized for the
Guy Bouchoux et al.
The journal of physical chemistry. A, 109(51), 11851-11859 (2005-12-22)
The gas-phase basicities of a representative set of hydroxy- and methoxycarbonyl compounds (hydroxyacetone, 1, 3-hydroxybutanone, 2, 3-hydroxy-3-methylbutanone, 3, 1-hydroxy-2-butanone, 4, 4-hydroxy-2-butanone, 5, 5-hydroxy-2-pentanone, 6, methoxyacetone, 7, 3-methoxy-2-butanone, 8, 4-methoxy-2-butanone, 9, and 5-methoxy-2-pentanone, 10) were experimentally determined by the equilibrium method
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