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Merck
CN

178314

N-Aminophthalimide

technical grade, 90%

Synonym(s):

N,N-Phthaloylhydrazine, unsym.

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About This Item

Empirical Formula (Hill Notation):
C8H6N2O2
CAS Number:
1875-48-5
Molecular Weight:
162.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24850729
EC Number:
217-505-9
Beilstein/REAXYS Number:
383756
MDL number:
MFCD00005895
Assay:
90%
Form:
powder

Key Documents

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Product Name

N-Aminophthalimide, technical grade, 90%

InChI key

KSILMCDYDAKOJD-UHFFFAOYSA-N

InChI

1S/C8H6N2O2/c9-10-7(11)5-3-1-2-4-6(5)8(10)12/h1-4H,9H2

SMILES string

NN1C(=O)c2ccccc2C1=O

grade

technical grade

assay

90%

form

powder

mp

200-202 °C (lit.)

functional group

imide

Quality Level

200

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Application

N-Aminophthalimide was employed in the aziridination of chiral N-enoyl sultams. It was also used in the synthesis of n-phthalimidoaziridines.

Other Notes

Remainder phthalhydrazide

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCH0001
BCCH0002
BCCJ1518
BCCC1503
BCBZ4343

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Kung-Shou Yang et al.
Organic letters, 4(7), 1107-1109 (2002-04-02)
[reaction: see text] Reaction of various N-enoyl oxazolidinones 5a-f with N-aminophthalimide and lead tetraacetate in the presence of camphor-derived chiral ligands provides the desired N-phthalimidoaziridines 6a-f in good to high enantiomeric excess (67-95% ee) at 0 degrees C within 15
Journal of the Chemical Society. Chemical Communications, 1074-1074 (1993)

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