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178314

N-Aminophthalimide

Name: <I>N</I>-Aminophthalimide
Brand: ALDRICH

technical grade, 90%

Synonym(s):

N,N-Phthaloylhydrazine, unsym.

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About This Item

Empirical Formula (Hill Notation):

C₈H₆N₂O₂

CAS Number:

1875-48-5

Molecular Weight:

162.15

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24850729

EC Number:

217-505-9

Beilstein/REAXYS Number:

383756

MDL number:

MFCD00005895

Assay:

90%

Form:

powder

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Properties

grade

technical grade

Quality Level

200

assay

90%

form

powder

mp

200-202 °C (lit.)

functional group

imide

SMILES string

NN1C(=O)c2ccccc2C1=O

InChI

1S/C8H6N2O2/c9-10-7(11)5-3-1-2-4-6(5)8(10)12/h1-4H,9H2

InChI key

KSILMCDYDAKOJD-UHFFFAOYSA-N

Description

Application

N-Aminophthalimide was employed in the aziridination of chiral N-enoyl sultams. It was also used in the synthesis of n-phthalimidoaziridines.

Other Notes

Remainder phthalhydrazide

pictograms

GHS08,GHS07

signalword

Danger

hcodes

H315,H317,H319,H334,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Journal of the Chemical Society. Chemical Communications, 1074-1074 (1993)

Enantioselective aziridination of alkenes with N-aminophthalimide in the presence of lead tetraacetate-mediated chiral ligand.

Kung-Shou Yang et al.

Organic letters, 4(7), 1107-1109 (2002-04-02)

[reaction: see text] Reaction of various N-enoyl oxazolidinones 5a-f with N-aminophthalimide and lead tetraacetate in the presence of camphor-derived chiral ligands provides the desired N-phthalimidoaziridines 6a-f in good to high enantiomeric excess (67-95% ee) at 0 degrees C within 15

Global Trade Item Number

SKU	GTIN
PH006477-5MG	04061822832527
178314-5G	04061831809930
178314-25G	04061831818994