181374
Polybutadiene, cis
average Mw 200,000-300,000
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About This Item
Linear Formula:
(CH2CH=CHCH2)n
CAS Number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
MDL number:
Product Name
Polybutadiene, cis, average Mw 200,000-300,000
SMILES string
C\C=C\C
InChI
1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+
InChI key
IAQRGUVFOMOMEM-ONEGZZNKSA-N
description
98% cis
form
slab/chunk
mol wt
average Mw 200,000-300,000
viscosity
40, Mooney(lit.)
transition temp
Tg −102 °C
density
0.9 g/mL at 25 °C (lit.)
Quality Level
Related Categories
Application
PB-cis can be polymerized with styrene for the formation of high impact polystyrene (HIPS). It may also be used as a toughening agent for acrylonitrile butadiene rubber (ABS) based resins.
General description
Polybutadiene, cis (PB-cis) is a synthetic rubber that is prepared by solution polymerization of 1,4-butadiene. Its mechanical properties include low temperature flexibility and abrasion resistance. It can be cured by using sulfur based donors and peroxides and thus PB-cis acts as a highly cross-linked polymer with high resilience.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Handbook of Poylmer-Liquid Interaction Parameters and Solubility Parameters (2018)
Rubber Basics, 80-81 (2002)
Morphological, mechanical properties, and fracture behavior of bulk-made ABS resins toughened by high-cis polybutadiene rubber
Yu Z, et al.
Polym. Eng. Sci., 50(5), 961-969 (2010)
Role of the rubber particle and polybutadiene cis content on the toughness of high impact polystyrene
Rovere J, et al.
Journal of materials science & technology, 43(3), 952-959 (2008)
Dong Wu et al.
Journal of the American Chemical Society, 132(45), 15936-15938 (2010-10-28)
Single-molecule force spectroscopy is used to observe the irreversible extension of a gem-dibromocyclopropane (gDBC)-functionalized polybutadiene under tension, a process akin to polymer necking at a single-molecule level. The extension of close to 28% in the contour length of the polymer
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