181382
Polybutadiene
average Mw ~200,000
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About This Item
Linear Formula:
(CH2CH=CHCH2)n
CAS Number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
MDL number:
InChI
1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+
InChI key
IAQRGUVFOMOMEM-ONEGZZNKSA-N
form
slabs
mol wt
average Mw ~200,000
composition
cis-1,4, 36% , trans-1,4, 55% , vinyl, 9%
refractive index
n20/D 1.5178
transition temp
Tg −95 °C
solubility
cyclohexane: 8.38 (solubility parameter)
density
0.9 g/mL at 25 °C (lit.)
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General description
Polybutadiene is a synthetic rubber that is produced by solution polymerization of 1,3-butadiene. It has excellent mechanical properties which include low temperature flexibility and abrasion resistance. It can be cured by using sulfur based donors and peroxides to result in a highly cross-linked polymer with high resilience.
Application
Polybutadiene is mainly blended with natural rubber and styrene butadiene rubber in the manufacturing of tyres. It can also be used in the development of conveyor and transmission belts.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Pyrolysis-thermogravimetric analysis of tyres and tyre components
Williams PT and Besler S
Fuel: The Science and Technology of Fuel and Energy, 74(9), 1277-1283 (1995)
Modification of butadiene-acrylonitrile rubber/poly (vinyl chloride) blend using natural rubber, styrene-butadiene rubber, and polybutadiene rubber
George KE, et al.
Polym. Eng. Sci., 27(15), 1137-1140 (1987)
Rubber Basics (2002)
Handbook of Poylmer-Liquid Interaction Parameters and Solubility Parameters (1990)
Zhi-ping Huang et al.
Journal of hazardous materials, 229-230, 251-257 (2012-06-26)
Migration appeared in the interfaces of nitrate ester plasticized polyether (NEPE) based propellant/hydroxyl-terminated polybutadiene (HTPB) based liner/ethylene propylene terpolymer (EPDM) based insulation was studied by aging at different temperatures. The migration components were extracted with solvent and determined by high
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