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183644

2-Bromonaphthalene

Name: 2-Bromonaphthalene
Brand: ALDRICH

97%

Synonym(s):

β-Bromonaphthalene, β-Naphthyl bromide, 2-Naphthyl bromide

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₇Br

CAS Number:

580-13-2

Molecular Weight:

207.07

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24851065

EC Number:

209-452-5

Beilstein/REAXYS Number:

1858110

MDL number:

MFCD00004051

Assay:

97%

Form:

solid

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Properties

Quality Level

100

assay

97%

form

solid

impurities

≤3% 1-bromonaphthalene

bp

281-282 °C (lit.)

mp

52-55 °C (lit.)

solubility

methanol: soluble 50 mg/mL, clear, colorless to yellow

functional group

bromo

SMILES string

Brc1ccc2ccccc2c1

InChI

1S/C10H7Br/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H

InChI key

APSMUYYLXZULMS-UHFFFAOYSA-N

Gene Information

human ... CYP2A6(1548)
mouse ... Cyp2a5(13087)

Description

General description

Reaction of 2-bromonaphthalene with cuprous cyanide in N-methylpyrrolidone has been investigated. Nanosecond time-resolved resonance Raman spectra of the T₁→T_n transition of 2-bromonaphthalene in methanol solvent has been investigated.

Application

2-Bromonaphthalene was used in the synthesis of biaryls via Suzuki cross coupling reaction in water under microwave irradiation.

pictograms

GHS07

signalword

Warning

hcodes

H302,H319

pcodes

P301 + P312 + P330 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Rapid microwave-promoted Suzuki cross coupling reaction in water.

Bai L, et al.

Green Chemistry, 5(5), 615-617 (2003)

Nanosecond time-resolved resonance Raman investigation of the T₁→ T_n transition of 2-bromonaphthalene.

Shoute LCT, et al.

Chemical Physics Letters, 290(1), 24-28 (1998)

Notes-A Convenient Synthesis of Water-Soluble Carbodiimides.

Sheehan J, et al.

The Journal of Organic Chemistry, 26(7), 2525-2528 (1961)

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Global Trade Item Number

SKU	GTIN
183644-5G	04061838756282
183644-25G	04061838346674