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Merck
CN

185442

Hexachloroethane

99%

Synonym(s):

Perchloroethane

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About This Item

Linear Formula:
Cl3CCCl3
CAS Number:
Molecular Weight:
236.74
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39050109
UNSPSC Code:
12352100
EC Number:
200-666-4
MDL number:
Beilstein/REAXYS Number:
1740341
Assay:
99%
Form:
solid
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InChI key

VHHHONWQHHHLTI-UHFFFAOYSA-N

InChI

1S/C2Cl6/c3-1(4,5)2(6,7)8

SMILES string

ClC(Cl)(Cl)C(Cl)(Cl)Cl

vapor density

8.16 (vs air)

vapor pressure

0.4 mmHg ( 20 °C)

assay

99%

form

solid

mp

183-185 °C (dec.) (lit.)

solubility

alcohol: soluble, benzene: soluble, chloroform: soluble, diethyl ether: soluble, oil: soluble, water: insoluble

density

2.091 g/mL at 25 °C (lit.)

functional group

chloro

Quality Level

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General description

Effect of hydrogen peroxide concentrations on the degradation of hexachloroethane in the absence and the presence of tetrachloroethene by Fenton′s reagent has been investigated.

Application

Hexachloroethane was used as catalyst in preparation of chlorosilanes from hydrosilanes. It was used to investigate the transformation of hexachloroethane in natural waters. It was used as reagent during polycondensation reaction of p-aminobenzoic acid.

signalword

Warning

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品
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Synthesis of Poly (p-benzamide) with Triphenylphosphine and Hexachloroethane Reagents-Reaction Conditions.
Wu G-C, et al.
Polymer Journal, 14(7), 571-574 (1982)
Transformation of hexachloroethane in a sulfidic natural water.
Miller PL, et al.
Environmental Science & Technology, 32(9), 1269-1275 (1998)
Veerachai Pongkittiphan et al.
Tetrahedron letters, 50(36), 5080-5082 (2010-04-03)
A new and efficient chlorination protocol is presented for the preparation of chlorosilanes from hydrosilanes. A variety of chlorinating agents in combination with palladium(II) chloride as the catalyst are examined. Among them, hexachloroethane is found to be the best choice
P S Holmes
Military medicine, 164(10), 751-752 (1999-11-02)
Hexachloroethane (HC) smoke, also known as white smoke, is an obscurant used in numerous military situations. Many adverse health effects are associated with the use of white smoke, some of which are potentially life threatening. Inhalation is the most frequent
Ludwig Weissflog et al.
Chemosphere, 65(6), 975-980 (2006-05-06)
Artemisia lerchiana is a wormwood species of the Central Asian steppe regions, where it completely cover whole areas. For the first time it was possible to show through field experiments that C(1)/C(2) halocarbons (VCHCs), such as chloroform (CHL), tetrachloroethene (PER)

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