186228
2′-Aminoacetophenone hydrochloride
95%
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About This Item
Linear Formula:
CH3COC6H4NH2 · HCl
CAS Number:
Molecular Weight:
171.62
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
95%
form
solid
mp
285-289 °C (lit.)
functional group
ketone
SMILES string
Cl.CC(=O)c1ccccc1N
InChI
1S/C8H9NO.ClH/c1-6(10)7-4-2-3-5-8(7)9;/h2-5H,9H2,1H3;1H
InChI key
APTPPYQXBFFQHZ-UHFFFAOYSA-N
Application
2′-Aminoacetophenone hydrochloride was used in the synthesis of α-benzamidoacetophenone and indazoles.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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The Preparation of Indazoles Via Metal Free Intramolecular Electrophilic Amination of 2-Aminophenyl Ketoximes.
M Counceller C, et al.
Organic Syntheses, 33-41 (2012)
Chloramphenicol1 (Chloromycetin). VI. A Synthetic Approach.
Long LM and Troutman HD.
Journal of the American Chemical Society, 71(7), 2469-2472 (1949)
Madhushree Y Gokhale et al.
Journal of pharmaceutical sciences, 98(12), 4639-4649 (2009-06-25)
Glycosylation reaction kinetics of a series of aromatic amines (kynurenine, 2'-aminoacetophenone, daptomycin, and sulfamethoxazole) was compared to propose a unifying reaction mechanism. Kinetic studies were conducted in aqueous solutions containing glucose in the pH range 1-6.5 with 2'-aminoacetophenone and daptomycin.
Guogang Zhao et al.
Biotechnology letters, 26(16), 1255-1259 (2004-10-16)
A new isolate of Arthrobacter sulfureus , when incubated at 50 g resting cells (dry cell wt) l(-1) with 50 g glucose l(-1) and 1 g 2-aminoacetophenone l(-1) in 50 mm potassium buffer (pH 7, 4 ml) at 30 degrees
Amy Scott-Thomas et al.
Journal of breath research, 5(4), 046002-046002 (2011-06-28)
2-Aminoacetophenone can be detected in the breath of Pseudomonas aeruginosa colonized cystic fibrosis patients; however, low levels were also detected in a small proportion of healthy subjects. It was hypothesized that food, beverages, cosmetics or medications could be a source
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