186708
(S)-(+)-2-Amino-3-methyl-1-butanol
96%
Synonym(s):
L-Valinol
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About This Item
Linear Formula:
(CH3)2CHCH(NH2)CH2OH
CAS Number:
Molecular Weight:
103.16
UNSPSC Code:
12352104
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-975-5
Beilstein/REAXYS Number:
1719137
MDL number:
Product Name
(S)-(+)-2-Amino-3-methyl-1-butanol, 96%
InChI key
NWYYWIJOWOLJNR-RXMQYKEDSA-N
InChI
1S/C5H13NO/c1-4(2)5(6)3-7/h4-5,7H,3,6H2,1-2H3/t5-/m1/s1
SMILES string
CC(C)[C@H](N)CO
assay
96%
optical activity
[α]25/D +10°, c = 10 in H2O
optical purity
ee: 95% (GLC)
refractive index
n20/D 1.4548 (lit.)
bp
81 °C/8 mmHg (lit.)
mp
30-32 °C (lit.)
density
0.926 g/mL at 25 °C (lit.)
functional group
amine
hydroxyl
storage temp.
2-8°C
Quality Level
Related Categories
Application
(S)-(+)-2-Amino-3-methyl-1-butanol can be used to prepare:
- Imines and oxazolines by reacting with aldehydes and nitriles, respectively.
- Chiral oxazoline derived multidentate ligands containing cyclophosphazene moiety.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
172.4 °F - closed cup
flash_point_c
78 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Tetrahedron Letters, 34, 2015-2015 (1993)
Journal of the Chemical Society. Perkin Transactions 1, 192-192 (1989)
Carla Fernandes et al.
Chirality, 29(8), 430-442 (2017-06-14)
Six chiral derivatives of xanthones (CDXs) were covalently bonded to silica, yielding the corresponding xanthonic chiral stationary phases (XCSPs). The new XCSPs were packed into stainless-steel columns with 150 x 4.6 mm i.d. Moreover, the greening of the chromatographic analysis
Enantioselective palladium catalysed allylic substitution with thienyl oxazoline ligands
Frost CG and Williams JMJ
Tetrahedron Letters, 34(12), 2015-2018 (1993)
Asymmetric synthesis of alpha-substituted o-methoxybenzyl alcohols via stereoselective additions to kinetically resolved o-anisaldehyde (tricarbonyl) chromium
Davies SG and Goodfellow CL
Journal of the Chemical Society. Perkin Transactions 1, 1, 192-194 (1989)
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