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186708

(S)-(+)-2-Amino-3-methyl-1-butanol

Name: (<I>S</I>)-(+)-2-Amino-3-methyl-1-butanol
Brand: ALDRICH

96%

Synonym(s):

L-Valinol

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About This Item

Linear Formula:

(CH₃)₂CHCH(NH₂)CH₂OH

CAS Number:

2026-48-4

Molecular Weight:

103.16

UNSPSC Code:

12352104

NACRES:

NA.22

PubChem Substance ID:

24851236

EC Number:

217-975-5

Beilstein/REAXYS Number:

1719137

MDL number:

MFCD00064296

Assay:

96%

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Properties

assay

96%

optical activity

[α]25/D +10°, c = 10 in H₂O

optical purity

ee: 95% (GLC)

refractive index

n20/D 1.4548 (lit.)

bp

81 °C/8 mmHg (lit.)

mp

30-32 °C (lit.)

density

0.926 g/mL at 25 °C (lit.)

functional group

amine, hydroxyl

storage temp.

2-8°C

SMILES string

CC(C)[C@H](N)CO

InChI

1S/C5H13NO/c1-4(2)5(6)3-7/h4-5,7H,3,6H2,1-2H3/t5-/m1/s1

InChI key

NWYYWIJOWOLJNR-RXMQYKEDSA-N

Description

Application

(S)-(+)-2-Amino-3-methyl-1-butanol can be used to prepare:

Imines and oxazolines by reacting with aldehydes and nitriles, respectively.
Chiral oxazoline derived multidentate ligands containing cyclophosphazene moiety.

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Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

172.4 °F - closed cup

flash_point_c

78 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Tetrahedron Letters, 34, 2015-2015 (1993)

Journal of the Chemical Society. Perkin Transactions 1, 192-192 (1989)

Chiral multidentate oxazoline ligands based on cyclophosphazene cores: synthesis, characterization and complexation studies.

Dheeraj Kumar et al.

Dalton transactions (Cambridge, England : 2003), 43(37), 13899-13912 (2014-08-12)

Chiral oxazoline based bi and hexadentate ligands built on cyclophosphazene cores have been synthesized and characterized. (NPPh2)2[NP(m-OC6H4C(O)OCH3)2] (1) was prepared by the reaction of gem-(NPPh2)2(NPCl2) with methyl-3-hydroxy benzoate in the presence of Cs2CO3. Compound 1 was converted to the dicarboxylic

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Global Trade Item Number

SKU	GTIN
186708-1G	04061838758286
186708-25G	04061837638992
186708-5G	04061838758293