187070
2-Bromobenzyl bromide
98%
Synonym(s):
α,2-Dibromotoluene
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About This Item
Linear Formula:
BrC6H4CH2Br
CAS Number:
Molecular Weight:
249.93
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
222-334-8
Beilstein/REAXYS Number:
971015
MDL number:
Assay:
98%
Form:
solid
InChI key
LZSYGJNFCREHMD-UHFFFAOYSA-N
InChI
1S/C7H6Br2/c8-5-6-3-1-2-4-7(6)9/h1-4H,5H2
SMILES string
BrCc1ccccc1Br
assay
98%
form
solid
refractive index
n20/D 1.619 (lit.)
bp
129 °C/19 mmHg (lit.)
mp
29-32 °C (lit.)
solubility
dioxane: soluble 1 g/10 mL, clear, colorless
functional group
bromo
Quality Level
Related Categories
General description
2-Bromobenzyl bromide is a reagent used to protect ketones and aldehydes in their less reactive alcohol oxidation states and as a coupling component in various reactions.
Application
2-Bromobenzyl bromide was used in the synthesis of:
- substituted quinazolines and 1,2,3,4-tetrahydroquinazolines
- 2- and 3-substituted indenes
- tris-2-bromotribenzylamine
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Synthesis and structural studies of tris-2-chlorobenzylamine and tris-2-bromobenzylamine.
Chen Q, , et al.
Journal of Chemical Crystallography, 35(3), 177-181 (2005)
2-Bromobenzyl Bromide
Pfeifer LA
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Xuesen Fan et al.
Chemistry, an Asian journal, 9(3), 739-743 (2014-01-01)
An efficient synthesis of diversely substituted quinazolines and 1,2,3,4-tetrahydroquinazolines through copper-catalyzed tandem reactions of the readily available 2-bromobenzyl bromides, aldehydes, and aqueous ammonia or amines has been developed. By using ammonia and simple aliphatic amines as the nitrogen source, the
Efficient synthesis of 2-and 3-substituted indenes from 2-bromobenzyl bromide through an enolate alkylation/Cr (II)/Ni (II)-mediated carbonyl addition sequence.
Halterman RLand Zhu C.
Tetrahedron Letters, 40(42), 7445-7448 (1999)
Prachi Singh et al.
SLAS discovery : advancing life sciences R & D, 22(4), 440-446 (2017-03-23)
Analysis of interactions between molecules is of fundamental importance in life science research. In this study, we applied weak affinity chromatography, based on high-performance liquid chromatography and mass spectrometry, as a powerful tool for direct analysis of the components of
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
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