187410
5-Methyl-2-nitrobenzyl alcohol
98%
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About This Item
Linear Formula:
CH3C6H3(NO2)CH2OH
CAS Number:
Molecular Weight:
167.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
266-360-8
MDL number:
Assay:
98%
InChI key
IKEYTRGLCHZQHO-UHFFFAOYSA-N
InChI
1S/C8H9NO3/c1-6-2-3-8(9(11)12)7(4-6)5-10/h2-4,10H,5H2,1H3
SMILES string
Cc1ccc(c(CO)c1)[N+]([O-])=O
assay
98%
mp
66-67 °C (lit.)
functional group
hydroxyl, nitro
General description
5-Methyl-2-nitrobenzyl alcohol undergoes oxidation in the presence of ammonium chlorochromate adsorbed on montmorillonite K-10 to yield 5-methyl-2-nitrobenzaldehyde. It also undergoes oxidation with chromium trioxide-HZSM-5 zeolite under microwave irradiation on solventless system.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Remarkable fast microwave-assisted zeolite HZSM-5 catalyzed oxidation of alcohols with chromium trioxide under solvent-free conditions.
Heravi MM.
J. Chem. Res. Synop., 5, 334-335 (1999)
Ammonium chlorochromate adsorbed on montmorillonite K-10: Selective oxidation of alcohols under solvent-free conditions.
Heravi M M and Hydar KT.
J. Chem. Res. Synop., 10, 656-657 (1998)
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