188824
2-Biphenylmethanol
99%
Synonym(s):
2-Phenylbenzyl alcohol
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About This Item
Linear Formula:
C6H5C6H4CH2OH
CAS Number:
Molecular Weight:
184.23
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
220-892-7
MDL number:
InChI key
VKTQADPEPIVMHK-UHFFFAOYSA-N
InChI
1S/C13H12O/c14-10-12-8-4-5-9-13(12)11-6-2-1-3-7-11/h1-9,14H,10H2
SMILES string
OCc1ccccc1-c2ccccc2
assay
99%
form
solid
bp
96 °C/0.04 mmHg (lit.)
mp
46-48 °C (lit.)
General description
2-Biphenylmethanol exhibits the formation of a new phase in a supercooled liquid state which was studied by differential scanning calorimetry and x-ray diffraction measurements. On heating 2-biphenylmethanol undergoes transformation from the glassy to liquid phase which has been investigated by luminescence spectra.
Application
2-Biphenylmethanol was used in the synthesis of o-ethynylbiphenyl and o-alkynylstyrene derivatives.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Annulation selectivity in the coupling of Fischer carbene complexes with o-alkynylbiphenyl and o-alkynylstyrene derivatives.
Jackson TJ and Herndon JW.
Tetrahedron, 57(18), 3859-3868 (2001)
Metastable polymorph formation in a supercooled liquid 2-biphenylmethanol: Luminescence study.
Baran J, et al.
Journal of Molecular Liquids, 153(2), 174-177 (2010)
Experimental evidence of formation of a new phase in supercooled liquid 2-biphenylmethanol.
Baran J, et al.
Journal of Physics. Condensed Matter : An Institute of Physics Journal, 18(24), 5695-5695 (2006)
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