189855
2,3-Dimethoxybenzylamine
99%
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About This Item
Linear Formula:
(CH3O)2C6H3CH2NH2
CAS Number:
Molecular Weight:
167.21
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
224-515-7
MDL number:
InChI key
LVMPWFJVYMXSNY-UHFFFAOYSA-N
InChI
1S/C9H13NO2/c1-11-8-5-3-4-7(6-10)9(8)12-2/h3-5H,6,10H2,1-2H3
SMILES string
COc1cccc(CN)c1OC
assay
99%
form
solid
refractive index
n20/D 1.54 (lit.)
bp
137 °C/11 mmHg (lit.)
density
1.13 g/mL at 25 °C (lit.)
Application
2,3-Dimethoxybenzylamine was used in the synthesis of di-,tri- and tetrapeptide linked dicatechol derivatives and 1-aryl-2,3-dihydro-1H-isoindoles (isoindolines).
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Facile synthesis of 1-aryl-2, 3-dihydro-1H-isoindoles by cyclization of N-formyliminium ion via geometrically disfavored 5-endo-trig process.
Kitabatake M, et al.
Heterocycles, 78(5), 1177-1181 (2009)
Di-, Tri-and tetrapeptide-linked dicatechol derivatives.
Albrecht M, et al.
Synthesis, 2002, 126-132 null
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