190616
2-Hydroxy-3-nitropyridine
98%
Synonym(s):
3-Nitro-2-pyridinol, 3-Nitro-2-pyridone
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About This Item
Empirical Formula (Hill Notation):
C5H4N2O3
CAS Number:
Molecular Weight:
140.10
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
228-709-2
Beilstein/REAXYS Number:
124474
MDL number:
Product Name
2-Hydroxy-3-nitropyridine, 98%
InChI key
BOAFCICMVMFLIT-UHFFFAOYSA-N
InChI
1S/C5H4N2O3/c8-5-4(7(9)10)2-1-3-6-5/h1-3H,(H,6,8)
SMILES string
Oc1ncccc1[N+]([O-])=O
assay
98%
mp
212 °C (dec.) (lit.)
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Application
2-Hydroxy-3-nitropyridine was used in the synthesis of:
- 3-nitro-2-pyridyl β-D-galactoside
- 3-nitro-2-pyridyl N-acetyl-β-D-glucosaminide
- 5-amino-6-chloro-3-iodopyridine
General description
2-Hydroxy-3-nitropyridine reacts with phosphorus pentachloride and phosphoryl chloride to yield 2-chloro-3-nitropyridine.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Nanjing Zhang et al.
Bioorganic & medicinal chemistry letters, 13(3), 525-527 (2003-02-05)
Racemic 5-azidoepibatidine [(+/-)-1] was synthesized via 5-aminoepibatidine as a candidate photoaffinity ligand with exceptionally high affinity at the mammalian neuronal nicotinic receptors (K(i) values of 0.027 nM for alpha 4 beta 2 and 9.7 nM for alpha 7) and excellent
Nitropyridyl glycosides: new glycosyl donors for enzymatic transglycosylation.
Yasukochi T, et al.
Tetrahedron Letters, 40(36), 6585-6589 (1999)
85. Nucleophilic displacement reactions in aromatic systems. Part I. Kinetics of the reactions of chloronitropyridines with aromatic amines and with pyridine.
Bishop RR, et al.
Journal of the Chemical Society, 437-446 (1952)
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