192201
2,4,6-Trimethylbenzenesulfonohydrazide
97%
Synonym(s):
2-Mesitylenesulfonohydrazide
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About This Item
Linear Formula:
(CH3)3C6H2SO2NHNH2
CAS Number:
Molecular Weight:
214.28
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
240-319-4
Beilstein/REAXYS Number:
2118380
MDL number:
Assay:
97%
InChI key
JQUBKTQDNVZHIY-UHFFFAOYSA-N
InChI
1S/C9H14N2O2S/c1-6-4-7(2)9(8(3)5-6)14(12,13)11-10/h4-5,11H,10H2,1-3H3
SMILES string
Cc1cc(C)c(c(C)c1)S(=O)(=O)NN
assay
97%
mp
112-114 °C (dec.) (lit.)
functional group
hydrazine
Application
2,4,6-Trimethylbenzenesulfonohydrazide has been used in the synthesis of:
- (E)-N′-(1-((1S*,4aR*,8aR*)-1-hydroxydecahydronaphthalen-4a-yl)ethylidene)-2,4,6-trimethylbenzenesulfonohydrazide
- complanadine alkaloids
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Concise Synthesis of 1, 4a-Bifunctionalised Decalin Building Blocks by CH Activation of Decalin.
Uosis-Martin M, et al.
Synlett, 2011(15), 2211-2213 (2011)
Mario Uosis-Martin et al.
The Journal of organic chemistry, 78(12), 6253-6263 (2013-05-30)
A synthetic approach to complanadine alkaloids is described which employs a Kondrat'eva reaction to construct the pyridine rings. The viability of this approach is demonstrated by its application to a model substrate accessed from unfunctionalized decalin. The key transformation affords
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