193011
2-Furaldehyde diethyl acetal
97%
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About This Item
Empirical Formula (Hill Notation):
C9H14O3
CAS Number:
Molecular Weight:
170.21
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
236-872-6
MDL number:
Assay:
97%
Form:
liquid
InChI key
SEILDMUKBMYIEZ-UHFFFAOYSA-N
InChI
1S/C9H14O3/c1-3-10-9(11-4-2)8-6-5-7-12-8/h5-7,9H,3-4H2,1-2H3
SMILES string
CCOC(OCC)c1ccco1
assay
97%
form
liquid
refractive index
n20/D 1.444 (lit.)
bp
189-191 °C (lit.)
density
1.008 g/mL at 25 °C (lit.)
functional group
ether
Application
2-Furaldehyde diethyl acetal was used in the synthesis of:
- 5-pyridyl- and 5-aryl-2-furaldehydes via Palladium-mediated cross-coupling reaction
- 11-oxatricyclo [5.3. 1.02, 6] undecane derivatives
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
147.2 °F - closed cup
flash_point_c
64 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Synthesis of 5-pyridyl-2-furaldehydes via palladium-catalyzed cross-coupling with triorganozincates.
Donald R Gauthier et al.
Organic letters, 4(3), 375-378 (2002-02-01)
5-Pyridyl- and 5-aryl-2-furaldehydes are prepared from furaldehyde diethyl acetal in a four-step, one-pot procedure:(i) deprotonation; (2) Li to Zn transmetalation; (3) Pd-mediated cross-coupling; (4) aldehyde deprotection. Triorganozincate 7 was found to transfer all three groups in the Pd-catalyzed cross-coupling reaction
Synthesis of 11-oxatricyclo [5.3. 1.02, 6] undecane derivatives via organometallic cyclizations.
La Belle BE, et al.
The Journal of Organic Chemistry, 50(25), 5215-5222 (1985)
Vijayakumar Karuppiah et al.
World journal of microbiology & biotechnology, 37(4), 66-66 (2021-03-20)
Pseudomonas aeruginosa is one of the vulnerable opportunistic pathogens associated with nosocomial infections, cystic fibrosis, burn wounds and surgical site infections. Several studies have reported that quorum sensing (QS) systems are controlled the P. aeruginosa pathogenicity. Hence, the targeting of
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