193704
2,4,5-Trimethyloxazole
95%
Synonym(s):
Trimethyloxazole
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About This Item
Empirical Formula (Hill Notation):
C6H9NO
CAS Number:
Molecular Weight:
111.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
243-952-4
MDL number:
Assay:
95%
Form:
liquid
InChI key
ZRLDBDZSLLGDOX-UHFFFAOYSA-N
InChI
1S/C6H9NO/c1-4-5(2)8-6(3)7-4/h1-3H3
SMILES string
Cc1nc(C)c(C)o1
assay
95%
form
liquid
refractive index
n20/D 1.442 (lit.)
bp
133-134 °C/760 mmHg (lit.)
density
0.957 g/mL at 25 °C (lit.)
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General description
2,4,5-Trimethyloxazole undergoes regio- and diastereoselective photocycloaddition reaction with aliphatic and aromatic aldehydes to yield erythro α-amino, β-hydroxy methyl ketones.
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Oxazole-Carbonyl photocycloadditions: selectivity pattern and synthetic route to erythro a-amino, ?-hydroxy ketones
Griesbeck AG, et al.
Chemical Communications (Cambridge, England), 589-590 (2000)
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