194751
N-tert-Butylhydroxylamine hydrochloride
≥98%
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About This Item
Linear Formula:
(CH3)3CNHOH · HCl
CAS Number:
Molecular Weight:
125.60
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
260-771-6
Beilstein/REAXYS Number:
3546053
MDL number:
Assay:
≥98%
Form:
solid
InChI key
DCSATTBHEMKGIP-UHFFFAOYSA-N
InChI
1S/C4H11NO.ClH/c1-4(2,3)5-6;/h5-6H,1-3H3;1H
SMILES string
Cl.CC(C)(C)NO
assay
≥98%
form
solid
mp
183-185 °C (lit.)
Quality Level
Application
N-tert-Butylhydroxylamine hydrochloride was used in spin trapping of short-lived radicals. It was also used in the synthesis of α-ketoamides and 3-spirocyclopropanated 2-azetidinones.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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A New Three-Component Cascade Reaction to Yield 3-Spirocyclopropanated?-Lactams.
Zanobini A, et al.
European Journal of Organic Chemistry, 2006(5), 1251-1255 (2006)
Ludmila A Voloboueva et al.
FASEB journal : official publication of the Federation of American Societies for Experimental Biology, 21(14), 4077-4086 (2007-07-28)
Age-related macular degeneration (AMD) is the leading cause of severe visual impairment in the elderly in developed countries. AMD patients have elevated levels of iron within the retinal pigment epithelia (RPE), which may lead to oxidative damage to mitochondria, disruption
C Lagercrantz
Free radical research communications, 14(5-6), 395-407 (1991-01-01)
Spin trapping of short-lived R. radicals is done by use of N-tert-butylhydroxylamine (1) and H2O2. The hydroxylamine is oxidized to the radical t-BuN(O)H (2) which is converted into the spin trap 2-methyl-2-nitrosopropane (3). Simultaneously, hydroxyl radicals .OH are formed from
Synthesis of alpha-ketoamides by a molecular-sieves-promoted formal oxidative coupling of aliphatic aldehydes with isocyanides.
Jean-Marie Grassot et al.
Angewandte Chemie (International ed. in English), 47(5), 947-950 (2007-12-20)
On the anti-aging activities of aminoguanidine and N-t-butylhydroxylamine.
A R Hipkiss
Mechanisms of ageing and development, 122(2), 169-171 (2001-02-13)
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