196223
B-Methoxy-9-BBN solution
1.0 M in hexanes
Synonym(s):
9-Methoxy-9-borabicyclo[3.3.1]nonane
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About This Item
Empirical Formula (Hill Notation):
C9H17BO
CAS Number:
Molecular Weight:
152.04
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Form:
liquid
InChI
1S/C9H17BO/c1-11-10-8-4-2-5-9(10)7-3-6-8/h8-9H,2-7H2,1H3/t8-,9+
SMILES string
COB1C2CCCC1CCC2
InChI key
UNGDGQYONLTNJZ-DTORHVGOSA-N
form
liquid
reaction suitability
reaction type: C-C Bond Formation
concentration
1.0 M in hexanes
density
0.716 g/mL at 25 °C
Application
- Pro-nucleophile and co-catalyst for indium-catalyzed allylations of methyl ethers and carbohydrate derivatives
- Catalyst for preparation of linear allenes from other allenes
Reactant for:
- Stereoconvergent Suzuki cross-coupling reactions
- B-alkyl Suzuki-Miyaura cross-coupling reactions
- Preparation of borabicyclononanyl amino acid complexes for selective treatment of malignant melanoma
- Asymmetric synthesis of isomerically pure allenyl boranes through insertion and borotropic rearrangement
signalword
Danger
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-14.8 °F - closed cup
flash_point_c
-26 °C - closed cup
Regulatory Information
危险化学品
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