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Merck
CN

196517

9-(Chloromethyl)anthracene

≥98%

Synonym(s):

9-Anthracenylmethyl chloride

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About This Item

Empirical Formula (Hill Notation):
C15H11Cl
CAS Number:
Molecular Weight:
226.70
EC Number:
246-274-7
UNSPSC Code:
12352103
PubChem Substance ID:
Beilstein/REAXYS Number:
1873394
MDL number:
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InChI key

PCVRSXXPGXRVEZ-UHFFFAOYSA-N

InChI

1S/C15H11Cl/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9H,10H2

SMILES string

ClCc1c2ccccc2cc3ccccc13

assay

≥98%

mp

138-140 °C (lit.)

Application

Protecting reagent for carboxylic acids, phenols, thiophenols, and mercaptans.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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A significant fluorescence quenching of anthrylaminobenzocrown ethers by paramagnetic metal cations
Chang, J. H., Choi, Y. M., & Shin, Y. K.
Bull. Korean Chem. Soc., 22(5), 527-530 (2001)
Clickable Poly (2-Oxazoline) s as Versatile Building Blocks.
Fijten, M. W., Haensch, C., van Lankvelt, B. M., Hoogenboom, R., & Schubert, U. S.
Macromolecular Chemistry and Physics, 209(18), 1887-1895 (2008)
9 (chloromethyl) anthracene: a useful derivatizing reagent for enhanced ultraviolet and fluorescence detection of carboxylic acids with liquid chromatography
Korte, W. D
Journal of Chromatography A, 243(1), 153-157 (1982)
Dorothea F K Rawn et al.
Journal of chromatography. A, 1080(2), 148-156 (2005-07-13)
A rapid and simple method for confirmation of the diarrhetic shellfish poisons (DSP): okadaic acid (OA), dinophysistoxin-1 (DTX-1) and dinophysistoxin-2 (DTX-2) using fluorescence detection following derivatization with 9-chloromethylanthracene, has been established as an alternate to LC/MS. Exposure of the anthrylmethyl
Zhenming Xie et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 857(1), 53-58 (2007-08-21)
A rapid and sensitive RP-HPLC method with fluorescence detection has been developed for the quantitative analysis of trace amounts of monofluoroacetate (MFA) in biological samples as serum, food and meat. 9-Chloromethylanthracene (9-CMA) is used as the fluorescence labeling reagent. Samples

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