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196657

1-Fluoronaphthalene

Name: 1-Fluoronaphthalene
Brand: ALDRICH

99%

Synonym(s):

α-Fluoronaphthalene

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₇F

CAS Number:

321-38-0

Molecular Weight:

146.16

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24851780

EC Number:

206-287-0

Beilstein/REAXYS Number:

1906413

MDL number:

MFCD00003873

Assay:

99%

Form:

liquid

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Properties

Quality Level

100

assay

99%

form

liquid

refractive index

n20/D 1.593 (lit.)

bp

215 °C (lit.)

mp

−13 °C (lit.)

density

1.1322 g/mL at 20 °C (lit.)

functional group

fluoro

SMILES string

Fc1cccc2ccccc12

InChI

1S/C10H7F/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H

InChI key

CWLKTJOTWITYSI-UHFFFAOYSA-N

Description

General description

Flash photolysis of O₂ and 1-fluoronaphthalene mixtures in the gas phase have been investigated.

Application

1-Fluoronaphthalene was used in t-BuLi-mediated synthesis of 6-substituted phenanthridines. It was also used in the synthesis of LY248686, a potent inhibitor of serotonin and norepinephrine uptake.

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pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

149.0 °F - closed cup

flash_point_c

65 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Formation of O ₂ (1Sigma g+) by 1-fluoronaphthalene sensitization.

Andrews LJ and Abrahamson EW.

Chemical Physics Letters, 10, 113-116 (1971)

A one-pot access to 6-substituted phenanthridines from fluoroarenes and nitriles via 1,2-arynes.

Jan Pawlas et al.

Organic letters, 4(16), 2687-2690 (2002-08-03)

[reaction: see text] A one-pot, t-BuLi-induced synthesis of 6-substituted phenanthridines from fluoroarenes and nitriles via 1,2-arynes is reported. Aryl- and hetaryl nitriles, cyanamides, and trimethylacetonitrile gave phenanthridine products. The method was extended to provide bisphenanthridine 10 by a one-pot bis-cyclization

Asymmetric synthesis and absolute stereochemistry of LY248686.

Deeter J, et al.

Tetrahedron Letters, 31(49), 7101-7104 (1990)

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Global Trade Item Number

SKU	GTIN
196657-25G	04061837071386
196657-5G	04061837071393