197637
Imidazole sodium derivative
technical grade
Synonym(s):
Imidazolylsodium, Sodium imidazolide
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About This Item
Empirical Formula (Hill Notation):
C3H3N2Na
CAS Number:
Molecular Weight:
90.06
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39161001
UNSPSC Code:
12352005
EC Number:
226-988-5
MDL number:
Beilstein/REAXYS Number:
3569312
Product Name
Imidazole sodium derivative, technical grade
InChI key
ITAWMPSVROAMOE-UHFFFAOYSA-N
InChI
1S/C3H3N2.Na/c1-2-5-3-4-1;/h1-3H;/q-1;+1
SMILES string
[Na]n1ccnc1
grade
technical grade
mp
284 °C (dec.) (lit.)
Quality Level
Related Categories
Application
Imidazole sodium derivative (Imidazolylsodium) was used in the synthesis of arylazidoamorphigenin.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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F G Earley et al.
The Biochemical journal, 224(2), 525-534 (1984-12-01)
A photoaffinity-labelling analogue of the respiratory inhibitor rotenone was synthesized from the naturally occurring rotenoid amorphigenin. The analogue inhibits NADH-ubiquinone oxidoreductase activity at concentrations comparable with those of rotenone. Photolysis of the radiolabelled analogue bound to isolated NADH-ubiquinone oxidoreductase resulted
Sun Un
Inorganic chemistry, 52(7), 3803-3813 (2013-03-21)
A common feature of a large majority of the manganese metalloenzymes, as well as many synthetic biomimetic complexes, is the bonding between the manganese ion and imidazoles. This interaction was studied by examining the nature and structure of manganese(II) imidazole
Chuanjiang Hu et al.
Inorganic chemistry, 52(6), 3170-3177 (2013-03-09)
The effects of the deprotonation of coordinated imidazole on the vibrational dynamics of five-coordinate high-spin iron(II) porphyrinates have been investigated using nuclear resonance vibrational spectroscopy. Two complexes have been studied in detail with both powder and oriented single-crystal measurements. Changes
Fei Yang et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(5), 1863-1868 (2013-01-16)
Many cancer therapeutics target DNA and exert cytotoxicity through the induction of DNA damage and inhibition of transcription. We report that a DNA minor groove binding hairpin pyrrole-imidazole (Py-Im) polyamide interferes with RNA polymerase II (RNAP2) activity in cell culture.
Yun Dai et al.
Electrophoresis, 34(6), 833-840 (2013-01-22)
The first member of the single-isomer, dicationic cyclodextrin (CD) family, 6(A)-ammonium-6(C)-butylimidazolium-β-cyclodextrin chlorides (AMBIMCD), has been synthesized, analytically characterized, and used to separate a variety of acidic enantiomers and amino acids by CE. Starting from mono-6(A)-azido-β-cyclodextrin, the cationic imidazolium and ammonium
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