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Merck
CN

197939

Borane tert-butylamine complex

97%, pellets, diam. 11 mm

Synonym(s):

tert-Butylamine borane, NSC 114045, Trihydro(2-methyl-2-propanamine) boron

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About This Item

Linear Formula:
(CH3)3CNH2 · BH3
CAS Number:
7337-45-3
Molecular Weight:
86.97
UNSPSC Code:
12352116
PubChem Substance ID:
24851852
EC Number:
230-851-5
MDL number:
MFCD00075635

Key Documents

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InChI key

GKFJEDWZQZKYHV-UHFFFAOYSA-N

InChI

1S/C4H11N.BH3/c1-4(2,3)5;/h5H2,1-3H3;1H3

SMILES string

B.CC(C)(C)N

assay

97%

form

pellets

reaction suitability

reagent type: reductant

diam.

11 mm

weight

~0.4 g (pellet)

mp

98-100 °C (dec.) (lit.)

Application

A water-soluble borane reducing agent
Reactant involved in:
  • Non-destructive analyses and conservation treatments of Indian drawings
  • Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes
  • The formation of σ-borane complexes
  • Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins
  • Photochemical hydroboration and oxidation of single-walled carbon nanotubes

pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
03713BP
61723EM

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Grant E Johnson et al.
Physical chemistry chemical physics : PCCP, 17(22), 14636-14646 (2015-05-15)
We present a systematic study of the effect of the number of methyl (Me) and cyclohexyl (Cy) functional groups in monodentate phosphine ligands on the solution-phase synthesis of ligated sub-nanometer gold clusters and their gas-phase fragmentation pathways. Small mixed ligand

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